Ruthenium(IV)Oxide Hydrate 氧化钌(IV)水合物
CAS 32740-79-7 MFCD00149846
化学结构图
SMILES: O.[O-2].[O-2].[Ru+4]
化学属性
| Mol. Formula | 2 |
|---|---|
| Mol. Weight | 151 |
| Melting Point | 1200° subl. |
| Solubility | Insoluble in water. Soluble in HCl |
| TSCA | Yes |
别名和识别编码
| Chemical Name | Ruthenium(IV)Oxide Hydrate |
|---|---|
| Synonym | Hydrous ruthenium oxide Ruthenium dioxide hydrate |
| MDL Number | MFCD00149846 |
| PubChem Substance ID | 24870094 |
| CAS Number | 32740-79-7 |
| EC Number | 234-840-6 |
| Chemical Name Translation | 氧化钌(IV)水合物 |
| LabNetwork Molecule ID | LN00226215 |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Metal and Ceramic Science, Oxides, Ru Catalysts, Ruthenium, Ruthenium Catalysts, 材料科学
- {SA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Oxides, Ru Catalysts, Ruthenium, Ruthenium Catalysts
相关文献及参考
- Fieser 1 ,984 / Fieser 12 ,428 / Fieser 17 ,304
- Corp MSDS 1 (2), 3061:A / RegBook 1 (3), 3287:F / Sax 6 , 2376
- Precursor for in situ generation of the powerful oxidant ruthenium(VIII) oxide (see Ruthenium(III) chloride hydrate, 11043): Helv. Chim. Acta, 71, 237 (1988). With Oxone. as stoichiometric oxidant in an acetonitrile/ ethyl acetate/ water solvent system, both terminal and internal alkynes can be cleaved to carboxylic acids in high yield: J. Org. Chem., 69, 2221 (2004). Mediates the electrooxidation of primary and secondary alcohols to aldehydes and ketones: Chem. Lett., 369 (1995).
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S17 Keep away from combustible material 远离可燃物料；
- R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
- R9 Explosive when mixed with combustible material 与易燃物混合会爆炸
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