Manganese(III) acetate dihydrate 醋酸锰

CAS 19513-05-4 MFCD00150022

化学结构图

19513-05-4
SMILES: O.O.CC(=O)O[Mn](OC(C)=O)OC(C)=O

化学属性

Mol. FormulaMn(OOCCH3)3?2H2O
Mol. Weight268.10
Density1.59
TSCAYes
Solubility分解

别名和识别编码

Chemical NameManganese(III) acetate dihydrate
Beilstein Registry Number3732626
PubChem Substance ID24852919
CAS Number19513-05-4
EC Number213-602-5
MDL NumberMFCD00150022
Synonym Manganese(III) acetate dihydrate Manganese triacetate dihydrate 醋酸锰(III) 二水合物
Chemical Name Translation醋酸锰
LabNetwork Molecule IDLN00200080
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分类

  • {SNA} Manganese, Micro/NanoElectronics, Solution Deposition Precursors, 材料科学
  • {SA} Manganese, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors
  • Manganese, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors

相关文献及参考

  • 3. J. Org. Chem. 62 , 6978, (1997)
  • Selective oxidizing agent in a variety of applications, usually involving free-radical mechanisms (compare Lead(IV)­ acetate, A15551). For brief reviews, see: J. Prakt. Chem./ Chem. Ztg., 339, 488 (1997); Synlett, 835 (2002). Examples:
  • Acetoxylation of benzylic or allylic C-H bonds: Chem. Commun., 507 (1970); J. Chem. Soc. (C), 2355 (1971); J. Org. Chem., 45, 3906 (1980); methylene groups ɑ- to a conjugated ketone can also be acetoxylated: Tetrahedron Lett., 25, 5839 (1984); Synthesis, 1119 (1990). For an improved procedure for the acetoxylation of enones in acetic acid, see: Tetrahedron, 60, 3427 (2004). Arylation of active methylene compounds: J. Org. Chem., 54, 2703, 2713 (1989). Reaction of olefins with carboxylic acids to give -lactones: J. Am. Chem. Soc., 96, 7977 (1974); J. Am. Chem. Soc., 106, 5384 (1984). Reaction with cyanoacetic or malonic acids gives the appropriate ɑ-substituted -lactones: Tetrahedron Lett., 26, 4291 (1985). For a review of Mn(III)-mediated reactions of unsaturated systems, see: Synthesis, 833 (1993). See also Diethyl­ allyl­malonate, L02286. For a review of Mn(III)-based oxidative free-radical cyclizations, see: Chem. Rev., 96, 339 (1996).
  • 2. Chem. Rev. 96 , 339, (1996) 摘要
  • With arylboronic acids the corresponding radicals are generated, which can couple with aromatic or heteroaromatic (furan, thiophene) solvents to give biaryls and heterobiaryls in good yields. Various sensitive functional groups are tolerated: J. Org. Chem., 68, 578 (2003).
  • With arylboronic acids the corresponding radicals are gene

安全信息

Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
WGK Germany3
GHS Symbol
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xn Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Hygroscopic

系列性分类


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