(+)-Tröger’s base

CAS 14645-24-0 MFCD00151116

化学结构图

14645-24-0
SMILES: CC1=CC2C[N@@]3C[N@@](CC4C=C(C)C=CC3=4)C=2C=C1

化学属性

Mol. FormulaC17H18N2
Mol. Weight250.34
Melting Point127-131 °C(lit.)

别名和识别编码

Chemical Name(+)-Tröger’s base
Synonym (5R,11R)-(+)-2,8-二甲基-6H,12H-5,11-亚甲基二苯并[b,f][1,5]二吖辛因 (+)-Tröger 碱
MDL NumberMFCD00151116
Beilstein Registry Number88612
CAS Number21451-74-1
PubChem Substance ID24865470
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Polyamines
  • {SNA} Analytical Reagents, Analytical/Chromatography, Chiral, Chiral Derivatization Reagents, Chiral LC Derivatization Reagents, Derivatization Reagents, Derivatization Reagents HPLC

相关文献及参考

  • 1. J. Org. Chem. 56 , 485, (1991)
  • Beil. 23 ,V,9,108
  • FT-NMR 1 (2), 665:C / RegBook 1 (1), 1531:I / Structure Index 1 , 239:D:2

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类


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