3-Quinuclidinol (第二类监控化学品，不能销售)奎宁环-3-醇
CAS 1619-34-7 MFCD00151326
化学结构图
SMILES: OC1CN2CCC1CC2
化学属性
| Mol. Formula | C7H13NO |
|---|---|
| Mol. Weight | 127.21 |
| Melting Point | 217-224° |
| TSCA | Yes |
| Solubility | 可溶 |
别名和识别编码
| Chemical Name | 3-Quinuclidinol |
|---|---|
| CAS Number | 1619-34-7 |
| Synonym | 3-QUINUCLIDINOL NSC 93905 3-Hydroxyquinuclidin 1-Azabicyclo(2.2.2)octan-3-ol (+/-)-1-Azabicyclo[2.2.2]octan-3-ol Quinuclidinol-3 1-氮杂双环[2.2.2]辛烷-3-醇 3-喹核醇 1-Azabicyclo[2.2.2.]-octan-3-ol dl-3-Quinuclidinol 1-Azabicyclo[2.2.2]octan-3-ol; 3-Hydroxyquinuclidine Quinuclidinol 3-羟基奎宁环 Quinuclidine-3-ol 1-Azabicyclo[2.2.2]octan-3-ol, 3-Hydroxyquinuclidine 3-Hydroxyquinuclidine, 1-Azabicyclo[2.2.2]octan-3-ol 1-Azabicyclo[2.2.2]octan-3-ol3-Hydroxyquinuclidine 3-HYDROXYQUINUCLIDINE 3-HYDROXYCHINUCLIDIN 3-Hydroxyquinuclidine 1-AZABICYCLO[2.2.2]OCTAN-3-OL 3-QUINUCLIDINOL (controlled chemical) 3-羟基奎宁 喹宁环-3-醇 1-氮杂二环[2.2.2]辛-3-醇 Quinuclidin-3-ol 98% 奎宁环-3-醇 3-喹核醇, 98+% 3-HYDROXYQUINUELIDINE 3-奎宁环醇 1-Azabicyclo[2.2.2]octan-3-ol 3-喹宁醇 QUINUCLIDIN-3-OL 3-QUINUCLIDINOL, 98+% (+/-)-3-Quinuclidinol 3-Hydroxyxinyclidine 3-Hydroxy-1-azabicyclo[2.2.2]octane |
| MDL Number | MFCD00151326 |
| EC Number | 216-578-4 |
| Merck Number | 14,8082 |
| Beilstein Registry Number | 0104327 |
| PubChem Substance ID | 15381 |
| Chemical Name Translation | (第二类监控化学品，不能销售)奎宁环-3-醇 |
| Wiswesser Line Notation | T66 A B CNTJ AQ |
| InChI | InChI=1S/C7H13NO/c9-7-5-8-3-1-6(7)2-4-8/h6-7,9H,1-5H2 |
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分类
- Heterocycles
- Pharmaceuticals
- Intermediates & Fine Chemicals,
- {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Quinuclidines
产品应用
- Hypotensive. Synthon for preparation of cholinergic receptor ligands and anesthetics.
相关文献及参考
- Rehavi, M., et al.: Life Sci., 21, 1293 (1977),
- Lockridge, O., et al.: NeuroToxicology, 21, 113 (2000),
- Kovarik, Z., et al.: Biochem. J., 373, 33 (2003),
- Reagent for selective cleavage of ß-keto esters to ketones in high yield: Synth. Commun., 5, 341 (1975). Geminal diesters are converted to monoesters in high yield under similar conditions: J. Org. Chem., 41, 208 (1976).
- Superior catalyst for the Baylis-Hillman reaction: the addition of acrylic esters to aldehydes, often very slow (4-7 days) with the usual catalyst 1,4-Diazabicyclo[2.2.2]octane, A14003, is much faster (<;1 day) in the presence of quinuclidinol: Synth. Commun., 18, 495 (1988); Tetrahedron Lett., 32, 5611 (1991). For more recent discussion and methodology, see: J. Org. Chem., 67, 510 (2002); 68, 692 (2003). For reviews of the Baylis-Hillman reaction, see: Tetrahedron, 44, 4653 (1988); 52, 8001 (1996). The rate of addition of enones to aldehydes is similarly enhanced: Synth. Commun., 18, 495 (1988); 19, 959 (1989).
安全信息
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R34 Causes burns 会导致灼伤
- R11 Highly flammable 非常易燃
GHS Symbol
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
TYPE OF TEST : Cytogenetic analysis ROUTE OF EXPOSURE : Intraperitoneal TEST SYSTEM : Rodent - hamster DOSE/DURATION : 10 mg/kg REFERENCE : ACNSAX Activitas Nervosa Superior. (Avicenum, Malostranske nam. 28, Prague 1, Czechoslovakia) V.1- 1959- Volume(issue)/page/year: 17,253,1975
其他信息
- 奎宁环-3-醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 132240050 奎宁环-3-醇 3-Quinuclidinol 99% 5 GR 328元 2010/06/21 132240250 奎宁环-3-醇 3-Quinuclidinol 99% 25 GR 1195元 2010/05/25 B21503 3-喹核醇, 98+% 3-Quinuclidinol, 98+% 25g 1145元
- F:34
- Acros Organics:3-喹宁醇 3-Quinuclidinol,99%(1619-34-7)
- 图谱信息:奎宁环-3-醇(1619-34-7)核磁图( 13 CNMR) 奎宁环-3-醇(1619-34-7)质谱(MS) 奎宁环-3-醇(1619-34-7)核磁图( 1 HNMR) 奎宁环-3-醇(1619-34-7)红外图谱(IR1) 奎宁环-3-醇(1619-34-7)红外图谱(IR2)
- Sigma Aldrich:1619-34-7(sigmaaldrich)
- Hazard Note:Corrosive
- Alfa Aesar:3-喹核醇,98+% 3-Quinuclidinol, 98+%(1619-34-7)
- MSDS 信息:3-Quinuclidinol(1619-34-7).msds
- MOL 文件:1619-34-7.mol
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