3-Chlorobenzeneboronic Acid 3-氯苯基硼酸

CAS 63503-60-6 MFCD00161354

化学结构图

63503-60-6
SMILES: OB(O)c1cccc(Cl)c1

化学属性

Mol. FormulaC6H6BClO2
Mol. Weight156
Melting Point185-189
TSCANo
Density1.32
Danger-Level甲类

别名和识别编码

Chemical Name3-Chlorobenzeneboronic Acid
CAS Number63503-60-6
Alfabeta NameCHLOROPHENYLBORONICACID 3-
MDL NumberMFCD00161354
Synonym (m-Chlorophenyl)boronic acid 3-Chlorobenzeneboronic acid m-Chlorobenzeneboronic acid 3-Chlorobenzeneboronic Acid (contains varying amounts of Anhydride) 3-Chlorophenylboronic acid 3-氯苯基硼酸 3-氯苯硼酸 间氯苯硼酸
PubChem Substance ID87566608
Reaxys-RN2936343
EC Number000-000-0
Beilstein Registry Number2936343
Chemical Name Translation3-氯苯基硼酸
LabNetwork Molecule IDLN00007815
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分类

  • {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
  • Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents

相关文献及参考

  • 1. H. Zilaout, et al., , The first examples of rhodium-catalyzed 1,4-conjugate addition reactions of arylboronic acids with ethenesulfonamides Tetrahedron Lett. 52 , 5934-5939, (2011)
  • 2. I. Ullah, et al., , Synthesis of trifluoromethyl-substituted di- and terphenyls by site-selective Suzuki-Miyaura reactions of 1,4-dibromo-2-trifluoromethyl-benzene Synlett 13 , 1895-1899, (2011)
  • 3. Y. Tsoi, et al., , Rhodium-Catalyzed Cross-Coupling Reaction of Arylboronates and Diazoesters and Tandem Alkylation Reaction for the Synthesis of Quaternary a,a -Heterodiaryl Carboxylic Esters Org. Lett. 13 , 5370-5373, (2011)
  • 4. E. Kianmehr and M. H. Baghersad, , Copper-Catalyzed Coupling of Arylboronic Acids with Potassium Cyanate: A New Approach to the Synthesis of Arylcarbamates Adv. Synth. Catal. 353 , 2599-2603, (2011)
  • 5. J. Karthikeyan, et al., , Synthesis of biarylketones and phthalides from organoboronic acids and aldehydes catalyzed by cobalt complexes Chem. Commun. 47 , 10461-10463, (2011)
  • 6. F. J. J. Bihel, et al., , New PDE4 inhibitors based on pharmacophoric similarity between papaverine and tofisopam Bioorg. Med. Chem. Lett. 21 , 6567-6572, (2011)
  • FT-IR 2 (3), 4463:C / Structure Index 1 , 479:A:6

安全信息

Warnings IRRITANT
WGK Germany3
GHS Symbol
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
Hazard Codes Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害

系列性分类


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