Bis((4R,5S)-4,5-diphenyl-4,5-dihydrooxazol-2-yl)methane 双((4R,5S)-4,5-二苯基-4,5-二氢恶唑-2-基)甲烷

CAS 139021-82-2 MFCD00192294

化学结构图

139021-82-2
SMILES: C(C1=N[C@@H]([C@@H](O1)C1C=CC=CC=1)C1C=CC=CC=1)C1=N[C@@H]([C@@H](O1)C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaC31H26N2O2
Mol. Weight458.55
Melting Point205-208 °C(lit.)

别名和识别编码

Chemical NameBis((4R,5S)-4,5-diphenyl-4,5-dihydrooxazol-2-yl)methane
Synonym (4R,5S,4′R,5′S)-2,2′-亚甲基双(4,5-二苯基-2-噁唑啉) 2,2′-亚甲基双[(4R,5S)-4,5-二苯基-2-噁唑啉]
MDL NumberMFCD00192294
PubChem Substance ID24865345
CAS Number139021-82-2
Beilstein Registry Number8941603
Chemical Name Translation双((4R,5S)-4,5-二苯基-4,5-二氢恶唑-2-基)甲烷
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分类

  • Asymmetric Synthesis, BOX, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • {SNA} Asymmetric Synthesis, BOX, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes

相关文献及参考

  • 1. Gant, T.G. Meyers, A.I. Tetrahedron 50 , 2297, (1994)
  • 2. Pfaltz, A. Acc. Chem. Res. 26 , 339, (1993)
  • 3. Bolm, C. Angew. Chem. Int. Ed. Engl. 30 , 542, (1991)
  • FT-IR 2 (2), 2215:A / Structure Index 1 , 236:D:8

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Oxazolines/Oxazolidines 恶唑啉/恶唑烷
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BOX - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BOX - Privileged Ligands and Complexes

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