1,2-Bis[(2S,5S)-2,5-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate 1,2-双[(2S,5S)-2,5-二甲基磷]苯(环辛二烯)三氟甲磺酸铑(I)

CAS 136705-75-4 MFCD00269863

化学结构图

136705-75-4
SMILES: [Rh+].C[C@H]1CC[C@H](C)P1C1C=CC=CC=1P1[C@@H](C)CC[C@@H]1C.[O-]S(=O)(=O)C(F)(F)F.C1CC=CCCC=C1

化学属性

Melting Point136.0-154.7 °C
Mol. FormulaC27H40F3O3P2RhS
Mol. Weight666.53
Appearance orange xtl.
Stabilityair sensitive, store cold

别名和识别编码

Chemical Name1,2-Bis[(2S,5S)-2,5-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Synonym 1,2-双[(2S,5S)-2,5-二甲基磷]苯(环辛二烯)三氟甲磺酸铑(I)
Chemical Name Translation1,2-双[(2S,5S)-2,5-二甲基磷]苯(环辛二烯)三氟甲磺酸铑(I)
PubChem Substance ID329760615
MDL NumberMFCD00269863
CAS Number136705-75-4
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. DuPhos/BPE - Privileged Ligands and Complexes
  1. BPE
  2. Rhodium
  1. DUPHOS
  2. Rhodium
  1. BPE
  2. 96-4731 (S,S)-Duphos and BPE Rhodium Catalyst Kit for Asymmetric Hydrogenation
  1. Catalysts
  2. 96-4731 (S,S)-Duphos and BPE Rhodium Catalyst Kit for Asymmetric Hydrogenation
  1. DUPHOS
  2. 96-4731 (S,S)-Duphos and BPE Rhodium Catalyst Kit for Asymmetric Hydrogenation
  1. Catalysts
  2. Rhodium
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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