Rac-Ethylenebis(tetrahydroindenyl)zirconium Dichloride [rac-乙烯双(4,5,6,7-四氢-1-茚基)]二氯化锆(IV)

CAS 100163-29-9 MFCD00672123

化学结构图

100163-29-9
SMILES: Cl[Zr]Cl.C(C[C]1[CH][CH][C]2CCCC[C]12)[C]1[CH][CH][C]2CCCC[C]12 |^1:5,6,7,8,13,14,15,16,17,22|

化学属性

Melting Point267-271 °C(lit.)
Mol. FormulaC20H24Cl2Zr
Mol. Weight426.54
Appearance white to pale yellow pwdr.
Stabilitymoisture sensitive

别名和识别编码

Chemical NameRac-Ethylenebis(tetrahydroindenyl)zirconium Dichloride
PubChem Substance ID24877859
Synonym [(S,S)-乙烯双(4,5,6,7-四氢-1-茚基)]二氯化锆(IV) Dichloro[rel-(7aR,7'aR)-1,2-ethanediylbis[(1,2,3,3a,7a-η)-4,5,6,7-tetrahydro-1H-inden-1-ylidene]]zirconium [(R,R)-乙烯双(4,5,6,7-四氢-1-茚基)]二氯化锆(IV) Dichloro[rel-(7aR,7′aR)-1,2-ethanediylbis[(1,2,3,3a,7a-η)-4,5,6,7-tetrahydro-1H-inden-1-ylidene]]zirconium [rac-乙烯双(4,5,6,7-四氢-1-茚基)]二氯化锆(IV)
Chemical Name Translation[rac-乙烯双(4,5,6,7-四氢-1-茚基)]二氯化锆(IV)
MDL NumberMFCD00672123
CAS Number100163-29-9
LabNetwork Molecule IDLN02124964
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Zirconium
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Other Chiral Catalysts
  • {SNA} Asymmetric Synthesis, Catalysts for Polymerization, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Olefin Polymerization, Other Chiral Catalysts, Polymer Science, Reagents for Polymerization, 材料科学

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Danger Warning
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Hazard Codes C Xi
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Other Chiral Catalysts - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Other Chiral Catalysts - Chiral Catalysts, Ligands, and Reagents
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Reagents for Polymerization - Polymer Science
  4. Catalysts for Polymerization - 烯烃聚合催化
  5. Olefin Polymerization - Catalysts for Polymerization
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Zirconium 锆x
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Zirconium 锆x
  1. Metallocenes, Derivatives & Cp Precursors
  2. Zirconium
  1. Catalysts
  2. Zirconium
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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