Bis(Pinacolato)Diboron 联硼酸频那醇酯

CAS 73183-34-3 MFCD00799570

化学结构图

73183-34-3
SMILES: CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C

化学属性

TSCANo
Mol. FormulaC12H24B2O4
Mol. Weight253.94
Density0.98
Appearance white to off-white xtl.
Stabilitymoisture sensitive
Melting Point137-140°C
Boiling Point222.6°C at 760 mmHg

别名和识别编码

Chemical NameBis(Pinacolato)Diboron
Alfabeta NameBISPINACOLATODIBORON ()
Synonym Bis(pinacolato)diborane {LY} Bis(pinacolato)diborane {} {LY} Bis(pinacolato)diborane {} {} {LY} Bis(pinacolato)diborane {} {} {} {LY} Bis(pinacolato)diborane {} {} {} {} {LY} Bis(pinacolato)diborane {} {} {} {} {} {LY} Bis(pinacolato)diborane {} {} {} {} {} {} {LY} Bis(pinacolato)diborane {} {} {} {} {} {} {} {LY} Bis(pinacolato)diborane {} {} {} {} {} {} {} {} {LY} Bis(pinacolato)diborane {} {} {} {} {} {} {} {} {} {LY} Bis(pinacolato)diborane {} {} {} {} {} {} {} {} {} {} {LY} Bis(pinacolato)diborane {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(pinacolato)diborane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(pinacolato)diborane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(pinacolato)diborane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(pinacolato)diborane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(pinacolato)diborane {} {} {} {} {} {} {} {} {} {} {} {} {}
Beilstein Registry Number7703552
EC Number250-023-7
PubChem Substance ID2733548
Reaxys-RN7703552
Merck Number1300
Chemical Name Translation联硼酸频那醇酯
LabNetwork Molecule IDLN00008537
InChIInChI=1S/C12H24B2O4/c1-9(2)10(3,4)16-13(15-9)14-17-11(5,6)12(7,8)18-14/h1-8H3
MDL NumberMFCD00799570
CAS Number73183-34-3
Canonical SMILESCC1(C)C(C)(C)OB(B2OC(C)(C)C(C)(C)O2)O1
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分类

  • Inhibitors
  • Heterocycles
  • {uni_hamburg} no charge; oxygen heterocycle; other heterocycle; alicycle; 5ring; 1fragment
  • {SNA} Chemical Reagents, Boronic Acids and Derivatives, Borylation Reagents, Chemical Synthesis, Development Quantities for Research, Organometallic Reagents
  • Pharmaceuticals
  • Intermediates & Fine Chemicals
  • {SNA} Boronic Acids and Derivatives, Borylation Reagents, Chemical Reagents, Chemical Synthesis, Development Quantities for Research, Organometallic Reagents
  • {SNA} Boronic Acids and Derivatives, Borylation Reagents, Chemical Synthesis, Organometallic Reagents

产品应用

  • 用于乙炔和石蜡（铂催化）的顺式-连位硼化试剂； 钯催化的芳香族化合物的硼化。
  • 钯催化的1,6-烯炔的环化生成高烯烷基硼酸盐（homoallylic alkylboronates）反应中的底物。

相关文献及参考

  • Short: III/35E
  • Merck: 14,1300
  • Ali, H.A. et al.: Arch. Pharm., 337, 183 (2004); Izumi, A. et al.: Chem. Lett., 7, 728 (2000);

安全信息

Warnings IRRITANT, IRRITANT-HARMFUL, KEEP COLD
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Signal word Warning
GHS Symbol
WGK Germany3
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P304+P340+P312
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P305+P351+P338
  • P332+P313
  • P302+P352+P312+P362+P364
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P305+P351+P338+P337+P313
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Hazard statements
  • H302+H312+H332
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Borylation Reagents - Boronic Acids and Derivatives
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Borylation Reagents - Boronic Acids and Derivatives
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronate Esters
  5. Heteroaryl
  1. Boronic Acid and Ester
  2. Boron