Dichloro [(R)-(+)-2,2’-Bis(Diphenylphosphino)-1,1’-Binaphathyl] Ruthenium(Ii) R-(+)-氯化钌BINAP

CAS 132071-87-5 MFCD01073794

化学结构图

132071-87-5
SMILES:

化学属性

Melting Point>;300 °C
Mol. FormulaC44H32Cl2P2Ru
Mol. Weight795
Appearance orange pwdr.
Stabilityair sensitive

别名和识别编码

Chemical NameDichloro [(R)-(+)-2,2’-Bis(Diphenylphosphino)-1,1’-Binaphathyl] Ruthenium(Ii)
Synonym (S)-[2,2′-双(二苯基膦)-1,1′-联萘]二氯化钌 (R)-BINAP 二氯化钌络合物 (R)-[1,1′-联萘]-2,2′-二基双[二苯膦]钌络合物 [(R)-[1,1′-Binaphthalene]-2,2′-diylbis[diphenylphosphine-κP]]dichloro-ruthenium (S)-BINAP 二氯化钌络合物 (S)-[1,1′-联萘]-2,2′-二基双[二苯膦]钌络合物 [(1S)-[1,1′-Binaphthalene]-2,2′-diylbis[diphenylphosphine-κP]]dichloro-ruthenium (R)-[2,2′-双(二苯基膦)-1,1′-联萘]二氯化钌
Reaxys-RN15397757
PubChem Substance ID329762304
Chemical Name TranslationR-(+)-氯化钌BINAP
MDL NumberMFCD01073794
CAS Number132071-87-5
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分类

  • Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydrogenation

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Hazard Codes Xi
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Hydrogenation - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BINAPs - Privileged Ligands and Complexes
  1. Functional Group 官能团索引
  2. phosphine
  1. BINAP
  2. Ruthenium
  1. Catalysts
  2. Ruthenium

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