Cobalt Oxide 四氧化三钴

CAS 1308-06-1 MFCD00010939

化学结构图

1308-06-1
SMILES: O=[Co].O=[Co]O[Co]=O

化学属性

Mol. Formula~Co3O4
Mol. Weight240.80
Density6.11 g/mL at 25 °C(lit.)
Melting Point895 °C (dec.) (lit.)
TSCAYes
SolubilitySoluble in acids and alkalies
Boiling Point3800 ºC
Stability对湿度敏感

别名和识别编码

Chemical NameCobalt Oxide
MDL NumberMFCD00010939
PubChem Substance ID11651651
CAS Number1308-06-1
EC Number215-157-2
Merck Number14,2429
Synonym 一氧化钴合三氧化二钴 四氧化三钴;氧化钴(II,III),,一氧化钴合三氧化二钴 氧化钴(II,III),,一氧化钴合三氧化二钴 Cobaltic-cobaltous oxide 四氧化三钴/纳米氧化钴 四氧化三钴(II,III) Cobalt tetraoxide Tricobalt tetroxide Cobalto-cobaltic oxide 四氧化三钴;氧化钴(II,III);一氧化钴合三氧化二钴 Cobalto-cobaltic tetroxide Cobalt oxide (II,III); Cobalt (+2) cobaltic (+3) oxide; Cobalto-cobaltic oxide Cobaltosic oxide Tricobalt tetraoxide
Chemical Name Translation四氧化三钴
LabNetwork Molecule IDLN00195227
InChIInChI=1S/3Co.4O
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分类

  • {SNA} 27: Co, Cobalt, Materials Science, Metal and Ceramic Science, Nanomaterials, Nanoparticles: Oxides, Nitrides, and Other Ceramics, Nanopowders and Nanoparticle Dispersions, Oxides
  • {SNA} 27: Co, Cobalt, Magnetic Materials, Materials Science, Metal and Ceramic Science,
  • {SNA} 27: Co,

产品应用

  • 主要用于电池材料、磁性材料、热敏电阻等; 也可用作催化剂机制作珐琅等

相关文献及参考

  • Merck: 14,2429

安全信息

WGK Germany1
Precautionary statements
  • P308+P313
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P304+P340
  • P342+P311
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Hazard statements
  • H350 May cause cancer 可能致癌
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H351 Suspected of causing cancer 怀疑致癌
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
Hazard Codes T Xn Xi
GHS Symbol
Signal word Danger Warning
RTECSGG2500000
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S22 Do not breathe dust 不要吸入粉尘;
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
UN Number UN3077
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R50/53
  • R42 May cause sensitisation by inhalation 吸入会产生过敏反应
  • R49 May cause cancer by inhalation 吸入会致癌
  • R52/53
Packing GroupIII
Storage condition 密封保存。
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1890 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CUTOEX Current Toxicology.  (Nova Science Publishers, Inc., 6080 Jericho
   Turnpike, Suite 207, Commack, NY  11725)  V.1    1993-
   Volume(issue)/page/year: 1,39,1993

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology,
   Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128)  V.1-
   1990-  Volume(issue)/page/year: 1,696,1992

其他信息

  • 能吸收水分而成水合物,但无固定组成。易被碳、一氧化碳或氢还原成钴。900℃以上时失去氧成为一氧化钴,在较低温时能吸收氧,结晶的结构不变。溶于酸和碱,几乎不溶于水。

系列性分类


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