3-Fluoro-4-methoxyphenylmagnesium bromide 3-氟-4-甲氧苯基溴化镁

CAS 112780-67-3 MFCD01311480

化学结构图

112780-67-3
SMILES: COC1=CC=C(C=C1F)[Mg]Br

化学属性

Mol. FormulaFC6H3(OCH3)MgBr
Mol. Weight229.33
Density0.964 g/mL at 25 °C(lit.)
Boiling Point65 °C(lit.)
TSCANo

别名和识别编码

Chemical Name3-Fluoro-4-methoxyphenylmagnesium bromide, 0.50 M in 2-MeTHF
MDL NumberMFCD01311480
PubChem Substance ID24880123
CAS Number112780-67-3
Synonym 3-氟-4-甲氧苯基溴化镁
Chemical Name Translation3-氟-4-甲氧苯基溴化镁
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分类

  • {SNA} Aryl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents

安全信息

WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S8 Keep container dry 保持容器干燥;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Packing GroupII
UN Number UN2924
Risk Statements
  • R11 Highly flammable 非常易燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R14 Reacts violently with water 遇水会猛烈反应
  • R34 Causes burns 会导致灼伤
  • R12 Extremely flammable 极端易燃
Storage condition Air & Moisture Sensitive
Hazard Codes F+,C F,Xn
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P370+P378
  • P403+P235
  • P301+P312+P330
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
Signal word Danger
Hazard statements
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害

系列性分类


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