(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) 环己二胺双(二叔丁基水杨烯)钴

CAS 188264-84-8 MFCD01631278

化学结构图

188264-84-8
SMILES: CC(C)(C)C1=CC(=CC2C=N[C@H]3CCCC[C@@H]3N=CC3C=C(C=C(C=3O[Co]OC=21)C(C)(C)C)C(C)(C)C)C(C)(C)C |c:6,21,23,t:4,9,18|

化学属性

Mol. FormulaC36H52CoN2O2
Mol. Weight603.76
Appearance red-brown pwdr.
Melting Point409-412°C

别名和识别编码

Chemical Name(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)
PubChem Substance ID24871025
Chemical Name Translation环己二胺双(二叔丁基水杨烯)钴
Synonym (S,S)-(+)-N,N′-双(3,5-二-叔丁基亚水杨基)-1,2-环己二胺钴(II)
MDL NumberMFCD01631278
CAS Number188264-84-8
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Kinetic Resolution, Privileged Ligands and Complexes, SALENs
  • {SA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Kinetic Resolution, Privileged Ligands and Complexes, SALENs

相关文献及参考

  • 1. Tokunaga, M. et al. Science 277 , 936, (1997) 摘要
  • 2. Jacobsen, E.N. et al. Tetrahedron Lett. 38 , 773, (1997)

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H311 Toxic in contact with skin 皮肤接触中毒
Hazard Codes Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Danger
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Kinetic Resolution - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. SALENs - Privileged Ligands and Complexes
  1. Jacobsen Ligand
  2. Cobalt
  1. Catalysts
  2. Cobalt

相关产品推荐