(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate (+)-1,2-双((2S,5S)-2,5-二甲基磷杂环戊烷)苯(1,5-环辛二烯)铑(I)四氟硼酸盐
CAS 205064-10-4 MFCD01862467
化学结构图
SMILES: C[C@H]1CC[C@H](C)P1c1ccccc1P1[C@@H](C)CC[C@@H]1C.F[B-](F)(F)F.[CH]1[CH]CC[CH][CH]CC1.[Rh+]
化学属性
| Mol. Formula | Rh(C8H12)(C18H28P2)+BF4ae |
|---|---|
| Mol. Weight | 604 |
| Appearance | red-orange xtl. |
| Stability | air sensitive |
别名和识别编码
| Chemical Name | (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate |
|---|---|
| Chemical Name Translation | (+)-1,2-双((2S,5S)-2,5-二甲基磷杂环戊烷)苯(1,5-环辛二烯)铑(I)四氟硼酸盐 |
| Synonym | 1,2-双[(2S,5S)-2,5-二甲基磷]苯(环辛二烯)四氟硼酸铑(I) |
| PubChem Substance ID | 16050141 |
| InChI | InChI=1S/C18H28P2.C8H12.BF4.Rh/c1-13-9-10-14(2)19(13)17-7-5-6-8-18(17)20-15(3)11-12-16(20)4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h5-8,13-16H,9-12H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;/t13-,14-,15-,16-;;;/m0.../s1 |
| MDL Number | MFCD01862467 |
| CAS Number | 205064-10-4 |
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分类
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes
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