N,N'-((1S,2S)-Cyclohexane-1,2-Diyl)Dipicolinamide S,S-环己二胺-N,N’-双(2-吡啶甲酰胺)

CAS 172138-95-3 MFCD02684544

化学结构图

172138-95-3
SMILES: O=C(N[C@H]1CCCC[C@@H]1NC(=O)C1C=CC=CN=1)C1C=CC=CN=1

化学属性

Mol. FormulaC18H20N4O2
Mol. Weight324.38
Appearance off-white pwdr.
Melting Point170°C

别名和识别编码

Chemical NameN,N'-((1S,2S)-Cyclohexane-1,2-Diyl)Dipicolinamide
Synonym (1S,2S)-N,N′-1,2-环己烷二基双(2-吡啶甲酰胺) (+)-N,N′-(1S,2S)-1,2-二氨基环己烷二基双(2-吡啶甲酰胺) (S,S)-DACH-吡啶基 Trost 配体 (+)-N,N′-(1S,2S)-1,2-二氨基环己烷二基双(2-吡啶甲酰胺) (1S,2S)-1,2-双(2-吡啶碳酰胺)环己烷 (1S,2S)-N,N′-1,2-环己烷二基双(2-吡啶甲酰胺) (1S,2S)-(+)-1,2-双[(2-吡啶基羰基)氨基]环己烷 (1S,2S)-1,2-双(2-吡啶碳酰胺)环己烷 (1S,2S)-(+)-1,2-双[(2-吡啶基羰基)氨基]环己烷
PubChem Substance ID329761524
Chemical Name TranslationS,S-环己二胺-N,N’-双(2-吡啶甲酰胺)
MDL NumberMFCD02684544
CAS Number172138-95-3
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Other Chiral Ligands
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, Trost Ligands

相关文献及参考

  • 1. Trost, B. M. et al. Chem. Rev. 96 , 395, (1996) 摘要
  • 2. Trost, B. M. et al. Chem. Rev. 103 , 2921, (2003) 摘要
  • 3. Trost, B. M. et al. J. Am. Chem. Soc. 124 , 11616, (2004)
  • 4. Trost, B. M. et al. Aldrichimica Acta 40 , 59, (2007)

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Hazard Codes Xn
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Other Chiral Ligands - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. Trost Ligands - Privileged Ligands and Complexes
  1. TROST
  2. Nitrogen
  1. Ligands
  2. Nitrogen

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