(S)-(+)-4,12-Bis(di-3,5-Xylylphosphino)[2.2]Paracyclophane, Cth-(S)-3,5-Xylyl-Phanephos (S)-(+)-4,12-双[二(3,5-二甲苯基)膦]-[2.2]-对环芳烷

CAS 325168-88-5 MFCD03840578

化学结构图

325168-88-5
SMILES: CC1=CC(C)=CC(=C1)P(C1C=C2CCC3C=CC(CCC=1C=C2)=CC=3P(C1=CC(C)=CC(C)=C1)C1=CC(C)=CC(C)=C1)C1=CC(C)=CC(C)=C1

化学属性

Melting Point234-238 °C
TSCANo
Mol. FormulaC48H50P2
Appearance white pwdr.
Mol. Weight689

别名和识别编码

Chemical Name(S)-(+)-4,12-Bis(di-3,5-Xylylphosphino)[2.2]Paracyclophane, Cth-(S)-3,5-Xylyl-Phanephos
Synonym (S)-xylyl-PHANEPHos (S)-5,11-双(3,5-二甲苯基膦)三环[8.2.24,7]十六-己烯 (R)-Xylyl-PHANEPhos (R)-5,11-双(3,5-二甲苯基膦)三环[8.2.2.24,7]十六-己烯 (R)-(–)-4,12-双[二(3,5-二甲苯基)膦]-[2.2]-对环芳烷 (S)-xylyl-PHANEPHos (S)-5,11-双(3,5-二甲苯基膦)三环[8.2.24,7]十六-己烯 (S)-(+)-4,12-双[二(3,5-二甲苯基)膦]-[2.2]-对环芳烷
PubChem Substance ID329760782
Chemical Name Translation(S)-(+)-4,12-双[二(3,5-二甲苯基)膦]-[2.2]-对环芳烷
MDL NumberMFCD03840578
CAS Number325168-88-5
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydrogenation, P-Phos, PhanePhos and BoPhoz Ligands, Privileged Ligands and Complexes
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydrogenation, P-Phos, PhanePhos and BoPhoz Ligands, Privileged Ligands and Complexes

相关文献及参考

  • 1. J. Am. Chem. Soc. 119 , 6207, (1997)
  • 2. Org. Lett. 2 , 4173, (2000) 摘要

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P305+P351+P338
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. P-Phos, PhanePhos and BoPhoz Ligands - Privileged Ligands and Complexes
  1. Functional Group 官能团索引
  2. phosphine
  1. PHANEPHOS
  2. Phosphorus
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus

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