(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 1,2-双[(2R,5R)-2,5-二苯基膦]乙烷(1,5-环辛二烯)四氟硼酸铑(I)

CAS 528565-84-6 MFCD07369037

化学结构图

528565-84-6
SMILES: [Rh+].F[B-](F)(F)F.C(CP1[C@H](CC[C@@H]1C1C=CC=CC=1)C1C=CC=CC=1)P1[C@H](CC[C@@H]1C1C=CC=CC=1)C1C=CC=CC=1.C1CC=CCCC=C1

化学属性

Mol. Formula[Rh(C8H12)(C34H36P2)]+BF4ae
Mol. Weight804
Appearance orange xtl.
Stabilityair sensitive

别名和识别编码

Chemical Name(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Synonym 1,2-双[(2R,5R)-2,5-二苯基膦]乙烷(1,5-环辛二烯)四氟硼酸铑(I) (R,R)-Ph-BPE-Rh
Chemical Name Translation1,2-双[(2R,5R)-2,5-二苯基膦]乙烷(1,5-环辛二烯)四氟硼酸铑(I)
PubChem Substance ID329762005
MDL NumberMFCD07369037
CAS Number528565-84-6
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Hazard Codes Xi
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. DuPhos/BPE - Privileged Ligands and Complexes
  1. BPE
  2. Rhodium
  1. DUPHOS
  2. Rhodium
  1. BPE
  2. 96-4730 (R,R)-Duphos and BPE Rhodium Catalyst Kit for Asymmetric Hydrogenation
  1. Catalysts
  2. 96-4730 (R,R)-Duphos and BPE Rhodium Catalyst Kit for Asymmetric Hydrogenation
  1. DUPHOS
  2. 96-4730 (R,R)-Duphos and BPE Rhodium Catalyst Kit for Asymmetric Hydrogenation
  1. Catalysts
  2. Rhodium

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