1,2-Bis[(2S,5S)-2,5-Diisopropylphospholano]Benzene(1,5-Cyclooctadiene)Rhodium(I) Tetrafluoroborate 1,2-双[(2S,5S)-2,5-二异丙基膦烷基]苯(1,5-环辛二烯)四氟硼酸铑(I)
CAS 1000393-36-1 MFCD07369040
化学结构图
SMILES:
化学属性
| Mol. Formula | C34H56BF4P2Rh |
|---|---|
| Stability | air sensitive |
| Appearance | red-orange xtl. |
| Mol. Weight | 716.47 |
别名和识别编码
| Chemical Name | 1,2-Bis[(2S,5S)-2,5-Diisopropylphospholano]Benzene(1,5-Cyclooctadiene)Rhodium(I) Tetrafluoroborate |
|---|---|
| CAS Number | 1000393-36-1 |
| Synonym | 1,2-双[(2S,5S)-2,5-二异丙基膦烷基]苯(1,5-环辛二烯)四氟硼酸铑(I) |
| Chemical Name Translation | 1,2-双[(2S,5S)-2,5-二异丙基膦烷基]苯(1,5-环辛二烯)四氟硼酸铑(I) |
| PubChem Substance ID | 329762003 |
| MDL Number | MFCD07369040 |
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分类
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes
相关文献及参考
- 1. Fox, M. E.; et al., Large-Scale Synthesis of a Substituted D-Phenylalanine Using Asymmetric Hydrogenation Org. Process Res. Dev. 15 , 1163-1171, (2011)
- 2. Qiu, L.; et al., Enantioselective hydrogenation of a-aminomethylacrylates containing a free N-H group for the synthesis of ß-amino acid derivatives Proc. Natl. Acad. Sci. U. S. A. 104 , 16787-16792, (2007)
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