Dichlorobis[2-(diphenylphosphino)ethylamine]ruthenium(II) 双[2-(二苯基膦)乙胺]二氯化钌(II)

CAS 506417-41-0 MFCD07782004

化学结构图

506417-41-0
SMILES: NCCP(C1C=CC=CC=1)C1C=CC=CC=1.NCCP(C1C=CC=CC=1)C1C=CC=CC=1.Cl[Ru]Cl

化学属性

Melting Point130-135 °C
Mol. FormulaRuCl2(C14H32NP)2
Appearance yellow pwdr.
Mol. Weight630

别名和识别编码

Chemical NameDichlorobis[2-(diphenylphosphino)ethylamine]ruthenium(II)
Synonym 二氯双(2-(二苯基膦)乙胺)钌(II) Dichlorobis[2-(diphenylphosphino-κP)ethanamine-κN]ruthenium
PubChem Substance ID24884703
Chemical Name Translation双[2-(二苯基膦)乙胺]二氯化钌(II)
MDL NumberMFCD07782004
CAS Number506417-41-0
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分类

  • Aminophosphine Ligands, Asymmetric Synthesis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, Ru Catalysts, Ruthenium
  • {SNA} Aminophosphine Ligands, Asymmetric Synthesis, Catalysis and Inorganic Chemistry, Chemical Synthesis,

相关文献及参考

  • 1. F. Stempfle, et al., Macromolecules 44 , 4159-4166, (2011)
  • 2. Y. Ino, et al., Top. Catal. 53 , 1019-1024, (2010)
  • 3. N. Blaquiere, et al., J. Am. Chem. Soc. 130 , 14034-14035, (2008)
  • 4. L. A. Saudan, et al., Angew. Chem. Int. Ed. Engl. 46 , 7473-7476, (2007)
  • 5. K. Abdur-Rashid, et al., Adv. Synth. Catal. 347 , 571-579, (2005)

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. Aminophosphine Ligands - Privileged Ligands and Complexes
  1. Catalysts
  2. Ruthenium

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