1,3-Di-Tert-Butyl-1H-Imidazol-3-Ium Tetrafluoroborate 1,3-二叔丁基-1H-咪唑-3-鎓四氟硼酸盐

CAS 263163-17-3 MFCD07784425

化学结构图

263163-17-3
SMILES: CC(C)(C)[N+]1=CN(C=C1)C(C)(C)C.F[B-](F)(F)F

化学属性

Melting Point157-198 °C
Mol. FormulaC11H21BF4N2
Mol. Weight268.10
Appearance white to cream-colored solid
Stabilityhygroscopic

别名和识别编码

Chemical Name1,3-Di-Tert-Butyl-1H-Imidazol-3-Ium Tetrafluoroborate
Synonym 1,3-双(叔丁基)-咪唑-2-四氟硼酸盐 N,N′-双(叔丁基)咪唑鎓四氟硼酸盐 1,3-二叔丁基咪唑鎓四氟硼酸盐
PubChem Substance ID87560610
Reaxys-RN8805202
Chemical Name Translation1,3-二叔丁基-1H-咪唑-3-鎓四氟硼酸盐
MDL NumberMFCD07784425
CAS Number263163-17-3
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分类

  • {SNA} Carbon-Donor Ligands, Catalysis and Inorganic Chemistry, Chemical Synthesis, NHC Compounds

相关文献及参考

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P303+P361+P353+P310+P363
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P304+P340+P310
  • P405 Store locked up. 上锁保管。
  • P304+P340
  • P303+P361+P353
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P301+P330+P331+P310
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Packing GroupIII
UN Number 1759
Hazard Class8

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. NHC Compounds - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Imidazoles 咪唑
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Buchwald Ligands Buchwald 膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Carbon-Donor Ligands 碳供体配体
  1. N-Heterocyclic Carbenes (NHCs)
  2. Nitrogen
  1. Ligands
  2. Nitrogen
  1. Ligands
  2. 96-3770 NHC Ligand Kit 3: Variety of N-Heterocyclic Carbenes
  1. N-Heterocyclic Carbenes (NHCs)
  2. Ligand Kit Variety of N-Heterocyclic Carbenes
  1. Ligands
  2. Nitrogen
  3. NHC Ligand

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