[1,3-Bis(2,6-Diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride [1,3-双(2,6-二异丙基苯基)咪唑-2-亚丙基](3-氯吡啶基)二氯化钯(II)

CAS 905459-27-0 MFCD08457656

化学结构图

905459-27-0
SMILES: CC(C)c1cccc(-n2ccn(-c3cccc(C(C)C)c3C(C)C)c2=[Pd-3](Cl)(Cl)c2ncccc2Cl)c1C(C)C

化学属性

Mol. FormulaC32H40Cl3N3Pd
Mol. Weight679.46
Melting Point230°C

别名和识别编码

Chemical Name[1,3-Bis(2,6-Diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride
Synonym Pd-PEPPSI-IPr {LY} Pd-PEPPSI-IPr {} {LY} Pd-PEPPSI-IPr {} {} {LY} Pd-PEPPSI-IPr {} {} {} {LY} Pd-PEPPSI-IPr {} {} {} {} {LY} Pd-PEPPSI-IPr {} {} {} {} {} {LY} Pd-PEPPSI-IPr {} {} {} {} {} {} {LY} Pd-PEPPSI-IPr {} {} {} {} {} {} {} {LY} Pd-PEPPSI-IPr {} {} {} {} {} {} {} {} {LY} Pd-PEPPSI-IPr {} {} {} {} {} {} {} {} {} {LY} Pd-PEPPSI-IPr {} {} {} {} {} {} {} {} {} {} {LY} Pd-PEPPSI-IPr {} {} {} {} {} {} {} {} {} {} {} {LY} Pd-PEPPSI-IPr {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pd-PEPPSI-IPr {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pd-PEPPSI-IPr {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pd-PEPPSI-IPr {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pd-PEPPSI-IPr {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pd-PEPPSI-IPr {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD08457656
PubChem Substance ID329760946
Chemical Name Translation[1,3-双(2,6-二异丙基苯基)咪唑-2-亚丙基](3-氯吡啶基)二氯化钯(II)
CAS Number905459-27-0
Canonical SMILESClC1=C[N]([Pd](Cl)(Cl)C2N(C3=C(C(C)C)C=CC=C3C(C)C)C=CN2C4=C(C(C)C)C=CC=C4C(C)C)=CC=C1
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分类

  • {SNA} ChemDose, Chemical Synthesis, Specialty Synthesis
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H351 Suspected of causing cancer 怀疑致癌
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr

系列性分类

  1. Chemical Synthesis 化学合成
  2. Specialty Synthesis 特殊合成技术
  3. ChemDose™ - Specialty Synthesis
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Palladium Catalysis 钯催化剂
  4. Homogeneous Pd Catalysts - Palladium

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