Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane Adduct 二(三甲基铝)-1,4-二氮杂二环[2.2.2]辛烷加合物

CAS 137203-34-0 MFCD09265160

化学结构图

137203-34-0
SMILES: C[Al-](C)(C)[N+]12CC[N+](CC1)(CC2)[Al-](C)(C)C

化学属性

Mol. FormulaC12H30Al2N2
Mol. Weight256
Melting Point>;250 °C

别名和识别编码

Chemical NameBis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane Adduct
Synonym DABAL-三甲基铝 DABAL-Me3 三亚乙基二胺基双三甲基铝 双(三甲基铝)-DABCO® 加合物 双(三甲基铝)-1,4-二氮杂双环[2.2.2]辛烷加合物
MDL NumberMFCD09265160
PubChem Substance ID24885678
Chemical Name Translation二(三甲基铝)-1,4-二氮杂二环[2.2.2]辛烷加合物
CAS Number137203-34-0
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分类

  • {SNA} Chemical Synthesis, DABAL - Me3, Greener Alternatives and Technologies, Greener Alternatives: Reagents, Organoaluminum, Organometallic Reagents
  • {SNA} Chemical Synthesis, Organoaluminum, Organometallic Reagents, Reproducibility: Validated Products, Verified by OrgSyn

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能,因为会剧烈反应可能产生闪火。
  • P422 Store contents under… 存储目录在…之下。
  • P231+P232
  • P305+P351+P338
  • P370+P378
Signal word Danger
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体,可自燃。
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes F,Xn
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
  • R14 Reacts violently with water 遇水会猛烈反应
  • R22 Harmful if swallowed 吞咽有害

系列性分类


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