(S)-5,5’-Bis[Di(3,5-Di-Tert-Butyl-4-Methoxyphenyl)Phosphino]-4,4’-Bi-1,3-Benzodioxole (S)-5,5’-双[二(3,5-二-T-丁基-4-甲氧基苯)磷]-4,4’-BI-1,3-苯二恶唑

CAS 210169-40-7 MFCD09753003

化学结构图

210169-40-7
SMILES: COc1c(C(C)(C)C)cc(P(c2cc(C(C)(C)C)c(OC)c(C(C)(C)C)c2)c2ccc3c(c2-c2c(P(c4cc(C(C)(C)C)c(OC)c(C(C)(C)C)c4)c4cc(C(C)(C)C)c(OC)c(C(C)(C)C)c4)ccc4c2OCO4)OCO3)cc1C(C)(C)C

化学属性

Mol. FormulaC74H100O8P2
Mol. Weight1179.53
Appearance off-white pwdr.
Melting Point126-128°C

别名和识别编码

Chemical Name(S)-5,5’-Bis[Di(3,5-Di-Tert-Butyl-4-Methoxyphenyl)Phosphino]-4,4’-Bi-1,3-Benzodioxole
Synonym (R)-(-)-5,5′-双[二(3,5-二叔丁基-4-甲氧基苯基)膦]-4,4′-二-1,3-苯并二噁茂 [(4R)-(4,4′-二-1,3-苯并二噁茂)-5,5′-二基]二[双(3,5--二叔丁基-4-甲氧基苯基)膦] (R)-DTBM-SEGPHOS® (S)-(+)-5,5′-双[二(3,5-二叔丁基-4-甲氧基苯基)膦]-4,4′-二-1,3-苯并二噁茂
Chemical Name Translation(S)-5,5’-双[二(3,5-二-T-丁基-4-甲氧基苯)磷]-4,4’-BI-1,3-苯二恶唑
Reaxys-RN22806358
PubChem Substance ID329761548
MDL NumberMFCD09753003
CAS Number210169-40-7
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, SEGPHOS
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, SEGPHOS

相关文献及参考

  • Duan, Z.-C.; et al., Cu-catalyzed asymmetric conjugate reduction of β-substituted α,β-unsaturated phosphonates: an efficient synthesis of optically active β-stereogenic Tetrahedron Lett. 50 , 6720-6722, (2009)
  • Moser, R.; et al., CuH-Catalyzed Enantioselective 1,2-Reductions of a,ß-Unsaturated Ketones J. Am. Chem. Soc. 132 , 7852-7853, (2010)
  • Nishida, G.; et al., Enantioselective synthesis of P-stereogenic alkynylphosphine oxides by Rh-catalyzed [2+2+2] cycloaddition Angew. Chem. Int. Ed. Engl. 47 , 3410-3413, (2008)
  • Seiser, T.; Cramer, N., Enantioselective C-C bond activation of allenyl cyclobutanes: access to cyclohexenones with quaternary stereogenic centers Angew. Chem. Int. Ed. Engl. 47 , 9294-9297, (2008)
  • Seiser, T.; Cramer, N., Rhodium(I)-Catalyzed Enantioselective Activation of Cyclobutanols: Formation of Cyclohexane Derivatives with Quaternary Stereogenic Centers Chem. Eur. J. 16 , 3383-3391, (2010)

安全信息

WGK Germany3

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. SEGPHOS® - Privileged Ligands and Complexes
  1. Phosphine
  2. Phosphorus
  1. SEGPHOS
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  1. Ligands
  2. 96-6900 Takasago SEGPHOS® Ligand Kit
  1. Phosphine
  2. 96-6900 Takasago SEGPHOS® Ligand Kit
  1. SEGPHOS
  2. 96-6900 Takasago SEGPHOS® Ligand Kit

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