Dichloro{(R)-2,2’-Bis[Di(3,5-Xylyl)Phosphino]-1,1’-Binaphthyl}[(2R)-1,1-Bis(4-Methoxyphenyl)-3-Methyl-1,2-Butanediamine]Ruthenium(II) 二氯[(R)-2,2′-二[二(3,5-二甲苯基)膦基]-1,1′-联萘基][(2R)-1,1-二(4-甲氧苯基)-3-甲基-1,2-丁二胺]钌(II)
CAS 220114-32-9 MFCD09753026
化学结构图
SMILES: CC(C)[C@@H](N)C(N)(C1=CC=C(C=C1)OC)C1=CC=C(C=C1)OC.CC1=CC(C)=CC(=C1)P(C1=CC(C)=CC(C)=C1)C1C=CC2C=CC=CC=2C=1C1=C(C=CC2C=CC=CC1=2)P(C1=CC(C)=CC(C)=C1)C1=CC(C)=CC(C)=C1.Cl[Ru]Cl
化学属性
| Melting Point | 197-211 °C |
|---|---|
| Mol. Formula | C71H74Cl2N2O2P2Ru |
| Mol. Weight | 1221.30 |
| Appearance | yellow to dark brown or green solid |
| Stability | air sensitive |
别名和识别编码
| Chemical Name | Dichloro{(R)-2,2’-Bis[Di(3,5-Xylyl)Phosphino]-1,1’-Binaphthyl}[(2R)-1,1-Bis(4-Methoxyphenyl)-3-Methyl-1,2-Butanediamine]Ruthenium(II) |
|---|---|
| Synonym | 二氯[(R)-(+)-2,2′-二[二(3,5-二甲苯基)膦基]-1,1′-联萘基][(2R)-(-)-1,1-二(4-甲氧苯基)-3-甲基-1,2-丁二胺]钌(II) RuCl2[(R)-DM-BINAP][(R)-DAIPEN] |
| Chemical Name Translation | 二氯[(R)-2,2′-二[二(3,5-二甲苯基)膦基]-1,1′-联萘基][(2R)-1,1-二(4-甲氧苯基)-3-甲基-1,2-丁二胺]钌(II) |
| PubChem Substance ID | 253659927 |
| MDL Number | MFCD09753026 |
| CAS Number | 220114-32-9 |
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分类
- Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
相关文献及参考
- Chen, C.; et al., Highly Enantioselective Hydrogenation of Aromatic-Heteroaromatic Ketones Org. Lett. 5 , 5039-5042, (2003)
- Maerten, E.; et al., Preparation of pyridinyl aryl methanol derivatives by enantioselective hydrogenation of ketones using chiral Ru(diphosphine)(diamine) complexes. Attribution of their absolute configuration by 1H NMR spectroscopy using Mosher's reagent Tetrahedron 64 , 8700-8708, (2008)
- O'Shea, P. D.; et al., Practical Asymmetric Synthesis of a Potent PDE4 Inhibitor via Stereoselective Enolate Alkylation of a Chiral Aryl-Heteroaryl Secondary Tosylate J. Org. Chem. 70 , 3021-3030, (2005)
- Ohkuma, T.; et al., Asymmetric Hydrogenation of Amino Ketones Using Chiral RuCl2(diphosphine)(1,2-diamine) Complexes J. Am. Chem. Soc. 122 , 6510-6511, (2000)
- Ohkuma, T.; et al., Asymmetric hydrogenation of 2-arylated cycloalkanones through dynamic kinetic resolution Synlett , 1383-1386, (2004)
- Ohkuma, T.; et al., General Asymmetric Hydrogenation of Heteroaromatic Ketones Org. Lett. 2 , 1749-1751, (2000)
- Takebayashi, S.; et al., Experimental Investigations of a Partial Ru-O Bond during the Metal-Ligand Bifunctional Addition in Noyori-Type Enantioselective Ketone Hydrogenation J. Am. Chem. Soc. 133 , 9666-9669, (2011)
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