[(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl]palladium(II) chloride [(S)-(-)-2,2′-双(二-对甲苯基膦)-1,1′-联萘]氯化钯(II)

CAS 215597-19-6 MFCD11656205

化学结构图

215597-19-6
SMILES: CC1C=CC(=CC=1)P(C1=CC=C2C=CC=CC2=C1C1C2=CC=CC=C2C=CC=1P(C1C=CC(C)=CC=1)C1C=CC(C)=CC=1)C1C=CC(C)=CC=1.Cl[Pd]Cl

化学属性

Mol. FormulaC48H40Cl2P2Pd
Mol. Weight856.10
Melting Point>;300 °C

别名和识别编码

Chemical Name[(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl]palladium(II) chloride
Synonym [PdCl2{(S)-4-tolylbinap}] [(R)-(+)-2,2′-双(二-对甲苯基膦)-1,1′-联萘]氯化钯(II) [(S)-(-)-2,2′-双(二-对甲苯基膦)-1,1′-联萘]氯化钯(II)
MDL NumberMFCD11656205
CAS Number215597-19-6
Chemical Name Translation[(S)-(-)-2,2′-双(二-对甲苯基膦)-1,1′-联萘]氯化钯(II)
PubChem Substance ID329762823
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分类

  • {SNA} Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes

相关文献及参考

  • 1. Lautens, M.; Hiebert, S., Scope of Palladium-Catalyzed Alkylative Ring Opening J. Am. Chem. Soc. 126 , 1437-1447, (2004)
  • 2. Bruyere, D.; et al., New developments in the Pd-catalyzed cyclization-coupling reaction of alkene-containing carbonucleophiles with organic halides (and triflates). The first examples of asymmetric catalysis. J. Organomet. Chem. 687 , 466-472, (2003)

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H302+H312+H332
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Hazard Codes Xn
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BINAPs - Privileged Ligands and Complexes

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