2,2,6,6-Tetramethylpiperidinylmagnesium Chloride lithium Chloride 2,2,6,6-四甲基哌啶基氯化镁氯化锂

CAS 898838-07-8 MFCD12546030

化学结构图

898838-07-8
SMILES: CC1(C)CCCC(C)(C)N1[Mg]Cl.[Cl-].[Li+]

化学属性

Density0.94
Mol. FormulaC9H18Cl2LiMgN
Mol. Weight242.4

别名和识别编码

Chemical Name2,2,6,6-Tetramethylpiperidinylmagnesium Chloride lithium Chloride
MDL NumberMFCD12546030
Synonym TMPMgCl·LiCl 2,2,6,6-四甲基哌啶基氯化镁氯化锂复合物 溶液
Chemical Name Translation2,2,6,6-四甲基哌啶基氯化镁氯化锂
PubChem Substance ID329762048
CAS Number898838-07-8
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分类

  • {SNA} Chemical Synthesis, Grignard Reagents, Heteroaryl, Organometallic Reagents
  • {SNA} 25mL Sure/Seal Reagents, Chemical Synthesis, Grignard Reagents, Heteroaryl, Organometallic Reagents

相关文献及参考

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P370+P378
  • P403+P235
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H302 Harmful if swallowed 吞食有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
Signal word Danger
Hazard Codes 4.3 F,C
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R34 Causes burns 会导致灼伤
  • R37 Irritating to respiratory system 刺激呼吸道
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
UN Number 3399
Packing GroupI
Restrict 危险品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Heteroaryl - Grignard Reagents

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