White-Chen catalyst (2S,2'S)-(-)-[N,N'-双(2-吡啶基甲基)-2,2'-联吡咯烷双(乙腈)六氟锑酸铁(II)
CAS 959395-10-9 MFCD16038114
化学结构图
SMILES:
化学属性
| Melting Point | >;300 °C |
|---|---|
| Mol. Formula | C24H32F12FeN6Sb2 |
| Mol. Weight | 931.90 |
| Appearance | purple pwdr. |
| Stability | air sensitive |
别名和识别编码
| Synonym | (2S,2′S-(-)-[N,N′-双(2-吡啶基甲基)]-2,2′-二吡咯烷双(乙腈)六氟锑酸铁(II) [Fe(S,S-PDP)(CH3CN)2](SbF6)2 (2R,2'R-(+)-[N,N'-Bis(2-pyridylmethyl)]-2,2'-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate (S,S-(2-({(S)-2-[(S)-1-(吡啶-2-基甲基)吡咯烷-2-基]吡咯烷-1-基}甲基)吡啶)(双-乙腈)六氟锑酸铁(II) Fe(S,S-PDP) White Catalyst White-Chen 催化剂 [Fe(S,S-PDP)(CH3CN)2](SbF6)2 Fe(R,R-PDP) Iron(II) (R,R-(2-({(R)-2-[(R)-1-(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl}methyl)pyridine)(bis-acetonitrile) hexafluoroantimonate White-Chen catalyst [Fe(R,R-PDP)(CH3CN)2](SbF6)2 White Catalyst White-Chen 催化剂 (S,S-(2-({(S)-2-[(S)-1-(吡啶-2-基甲基)吡咯烷-2-基]吡咯烷-1-基}甲基)吡啶)(双-乙腈)六氟锑酸铁(II) Fe(S,S-PDP) |
|---|---|
| Chemical Name | White-Chen catalyst |
| Chemical Name Translation | (2S,2'S)-(-)-[N,N'-双(2-吡啶基甲基)-2,2'-联吡咯烷双(乙腈)六氟锑酸铁(II) |
| PubChem Substance ID | 329764568 |
| MDL Number | MFCD16038114 |
| CAS Number | 959395-10-9 |
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分类
- {SNA} 12 Principles Aligned Products, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Greener Alternative Products, Iron, Non-Precious Metal Catalysis
- {SNA} 12 Principles Aligned Products, C-H Activation, Catalysis, Catalysis and Inorganic Chemistry, Catalysts,
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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