Thiazole-5-carboxaldehyde 5-噻唑甲醛

CAS 1003-32-3 MFCD02179516

化学结构图

1003-32-3
SMILES: O=Cc1cncs1

化学属性

Mol. FormulaC4H3NOS
Mol. Weight113.14
Density1.304 g/mL at 25 °C
Refractive index1.5820 to 1.5870
Flash Point98°C
Boiling Point92-94°C at 16 mmHg
TSCANo
Stability对空气敏感
Melting Point229 °C

别名和识别编码

Chemical NameThiazole-5-carboxaldehyde
CAS Number1003-32-3
Alfabeta NameTHIAZOLECARBALDEHYDE 135---,
MDL NumberMFCD02179516
EC Number250-023-7
Beilstein Registry Number2384789
Synonym Thiazole-5-carboxyaldehyde {LY} Thiazole-5-carboxyaldehyde {} {LY} Thiazole-5-carboxyaldehyde {} {} {LY} Thiazole-5-carboxyaldehyde {} {} {} {LY} Thiazole-5-carboxyaldehyde {} {} {} {} {LY} Thiazole-5-carboxyaldehyde {} {} {} {} {} {LY} Thiazole-5-carboxyaldehyde {} {} {} {} {} {} {LY} Thiazole-5-carboxyaldehyde {} {} {} {} {} {} {} {LY} Thiazole-5-carboxyaldehyde {} {} {} {} {} {} {} {} {LY} Thiazole-5-carboxyaldehyde {} {} {} {} {} {} {} {} {} {LY} Thiazole-5-carboxyaldehyde {} {} {} {} {} {} {} {} {} {} {LY} Thiazole-5-carboxyaldehyde {} {} {} {} {} {} {} {} {} {} {} {LY} Thiazole-5-carboxyaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thiazole-5-carboxyaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thiazole-5-carboxyaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thiazole-5-carboxyaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID2773577
Chemical Name Translation5-噻唑甲醛
Reaxys-RN107112
LabNetwork Molecule IDLN00002896
InChIInChI=1S/C4H3NOS/c6-2-4-1-5-3-7-4/h1-3H
Canonical SMILESO=CC1=CN=CS1
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分类

  • {SNA} Aldehydes, Building Blocks, C1 to C6, C3 to C7, Carbonyl Compounds, Chemical Synthesis, Heterocyclic Building Blocks, Organic Building Blocks, Thiazoles

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S24 Avoid contact with skin 避免皮肤接触；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36 Irritating to eyes 刺激眼睛
  • R22 Harmful if swallowed 吞咽有害
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P333+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard Codes Xn Xi,Xn
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Storage condition -20°C, sealed storage, away from moisture {LY} -20°C, sealed storage, away from moisture 0-10°C {} {LY} -20°C, sealed storage, away from moisture {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from m

其他信息

  • Sigma Aldrich:1003-32-3(sigmaaldrich)
  • 上游原料:甲醇 --> 二氯甲烷 --> N,N-二甲基甲酰胺 --> 石油醚 --> 硫酸钠 --> 碳酸氢钠 --> 氢 --> 醋酸钠 --> 氧溴化磷 --> 硫酸镁 --> 10%钯碳 --> 2,4-噻唑烷二酮
  • Hazard Note:Irritant
  • 存储注意事项:氮气保护
  • MOL 文件:1003-32-3.mol
  • 检测方法:HPLC,NMR

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Thiazoles 噻唑
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Thiazoles 噻唑
  5. C3 to C7 - Thiazoles

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