Methylenaminoacetonitrile 亚甲基氨基乙腈

CAS 109-82-0 MFCD00001889

化学结构图

109-82-0
SMILES: C=NCC#N

化学属性

Mol. FormulaC3H4N2
Mol. Weight68.08
Melting Point127-130 °C
TSCAYes
Appearance N-亚甲氨基乙腈(109-82-0)为三聚体。熔点129℃，白色斜方形结晶。能溶于热水、醇，微溶于苯。
Boiling Point106.45 °C at 760 mmHg

别名和识别编码

Chemical NameMethylenaminoacetonitrile
MDL NumberMFCD00001889
CAS Number109-82-0
Synonym 2-(Methylideneamino)acetonitrile {LY} 2-(Methylideneamino)acetonitrile {} {LY} 2-(Methylideneamino)acetonitrile {} {} {LY} 2-(Methylideneamino)acetonitrile {} {} {} {LY} 2-(Methylideneamino)acetonitrile {} {} {} {} {LY} 2-(Methylideneamino)acetonitrile {} {} {} {} {} {LY} 2-(Methylideneamino)acetonitrile {} {} {} {} {} {} {LY} 2-(Methylideneamino)acetonitrile {} {} {} {} {} {} {} {LY} 2-(Methylideneamino)acetonitrile {} {} {} {} {} {} {} {} {LY} 2-(Methylideneamino)acetonitrile {} {} {} {} {} {} {} {} {} {LY} 2-(Methylideneamino)acetonitrile {} {} {} {} {} {} {} {} {} {} {LY} 2-(Methylideneamino)acetonitrile {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Methylideneamino)acetonitrile {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Methylideneamino)acetonitrile {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Methylideneamino)acetonitrile {} {} {} {} {} {} {} {} {} {}
EC Number203-709-5
Merck Number6057
Beilstein Registry Number1848155
Reaxys-RN1848155
PubChem Substance ID8015
Chemical Name Translation亚甲基氨基乙腈
Wiswesser Line NotationNC1NU1
LabNetwork Molecule IDLN00239697
InChIInChI=1S/C3H4N2/c1-5-3-2-4/h1,3H2
Canonical SMILESC=NCC#N
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: III/5a Title: Structure Data of Organic Crystals: C ... C 13 Author: Schudt, E.; Weitz, G. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/5a Year: 1971 ISBN: 3-540-05177-5 ISBN: 978-3-540-05177-0 Internet Resource: DOI:10.1007/b19970 RefComment: XXI, 736 pages, and VII, 890 pages. Hardcover Abstract: Volume III/5 offers a compitation as complete as possible of the space groups and lattice con-stants of all crystals which have been studied by means of X-rays, neutron and electron diffraction.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSMC1925000
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Hazard Codes Xn
Signal word
Hazard statements
  • H302+H312+H332
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P312+P330
  • P302+P350
  • P337+P313
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P312+P362+P364
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P304+P340+P312
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P305+P351+P338+P337+P313
  • P305+P351+P338
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
GHS Symbol 
TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCNSA6 National Academy of Sciences, National Research Council,
   Chemical-Biological Coordination Center, Review.  (Washington, DC)
   Volume(issue)/page/year: 5,27,1953

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Parenteral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 7,689,1955

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

Storage condition

其他信息

  • Sigma Aldrich:109-82-0(sigmaaldrich)
  • TCI Shanghai:N-亚甲氨基乙腈 (Methyleneamino)acetonitrile,>;98.0%(N)(109-82-0)
  • MSDS 信息:N-Methylenaminoacetonitrile(109-82-0).msds
  • N-亚甲氨基乙腈价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0212 (亚甲氨基)乙腈 (Methyleneamino)acetonitrile 500G 2910元 2014/06/02 M0212 (亚甲氨基)乙腈 (Methyleneamino)acetonitrile 25G 315元 2010/05/25 A17162 亚甲基亚氨基乙腈, 98% Methyleneiminoacetonitrile, 98% 25g 370元
  • Alfa Aesar:亚甲基亚氨基乙腈,98% Methyleneiminoacetonitrile, 98%(109-82-0)
  • 图谱信息:N-亚甲氨基乙腈(109-82-0)质谱(MS) N-亚甲氨基乙腈(109-82-0)核磁图( 1 HNMR) N-亚甲氨基乙腈(109-82-0)红外图谱(IR2) N-亚甲氨基乙腈(109-82-0)红外图谱(IR1)
  • 下游产品:甘氨酸 --> 氨基乙腈
  • MOL 文件:109-82-0.mol
  • 方法一:在搅拌和维持0℃的条件下，，将氰化钠水溶液加入甲醛和氯化铵的混合物中，加料中途，同时滴加冰乙酸。加毕，搅拌1.5h，将沉淀滤出，水洗，干燥，得亚甲氨基乙腈，收率61-71%。
  • 用途一:有机合成中间体

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. ACS - Analytical Reagents for General Use

相关产品推荐