3-Pyrroline 3-吡咯啉

CAS 109-96-6 MFCD00005213

化学结构图

109-96-6
SMILES: C1=CCNC1

化学属性

Mol. FormulaC4
Mol. Weight69
Boiling Point90-91
Refractive index1.4610 to 1.4670
Density0.91
Flash Point-18°C(lit.)
TSCAYes
Solubility与水混溶，溶于乙醇、乙醚。
Melting Point-18
Stability对空气和湿度敏感

别名和识别编码

Chemical Name3-Pyrroline
CAS Number109-96-6
Alfabeta NamePYRROLINE 3-
MDL NumberMFCD00005213
Synonym 2,5-Dihydro-1H-pyrrole 3-吡咯啉 3-Pyrroline (contains Pyrrolidine) DIHYDROPYRROLE 3-吡咯啉 2,5-二氢吡咯 3-二氢吡咯 2,5-Dihydropyrrole 3-Pyrroline HCl 3-Pyrroline95% 2,5-Dihydropyrrol 2,5-二氢吡咯 2,5-dihydro-1h-pyrrol 2,5-二氢-1 H-吡咯 2,5-dihydro-H-pyrrole 3-Pyrroline, tech. 85% (remainder pyrrolidine) 3-吡咯啉, TECH. 85% (REMAINDER PYRROLIDINE) 2,5-DIHYDRO-1H-PYRROLE 3-PYRROLINE TECH ABOUT 70% 3-二氢吡咯 3-PYRROLINE delta3-Pyrroline 2,5-DIHYDROPYRROLE
PubChem Substance ID66059
EC Number203-723-1
Beilstein Registry Number103173
Merck Number8017
Reaxys-RN103173
Chemical Name Translation3-吡咯啉
LabNetwork Molecule IDLN00191851
InChIInChI=1S/C4H7N/c1-2-4-5-3-1/h1-2,5H,3-4H2
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Pyrrolines

产品应用

  • 储存温度-20°C

相关文献及参考

  • Merck:14,8017
  • Merck:14,8017 Beilstein:20(2)67

安全信息

Warnings KEEP COLD, FLAMMABLE, CORROSIVE
GHS Symbol
WGK Germany2
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H302+H332
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P370+P378
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupII
UN Number 2733 2924 UN 2733 3/PG 2 UN2733
Risk Statements
  • R11 Highly flammable 非常易燃
  • R12 Extremely flammable 极端易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R35 Causes severe burns 会导致严重灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Storage condition Air Sensitive & Hygroscopic Keep Cold 储存温度-20°C Air Sensitive
Hazard Codes 3 F,C
Hazard Class3/8

其他信息

  • 上游原料:氢氧化钠 --> 盐酸 --> 乙醚 --> 锌粉 --> 吡咯
  • TCI Shanghai:3-吡咯啉(含吡咯烷) 3-Pyrroline (contains Pyrrolidine),>;70.0%(GC)(109-96-6)
  • F:3-10-19-23
  • Sigma Aldrich:109-96-6(sigmaaldrich)
  • 3-吡咯啉价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 P0577 3-吡咯啉(含吡咯烷) 3-Pyrroline (contains Pyrrolidine) 5ML 1690元 2010/06/21 132132500 3-吡咯啉 3-Pyrroline 97% 250 MG 583元 2010/06/21 132130010 3-吡咯啉 3-Pyrroline 97% 1 GR 1668元
  • Alfa Aesar:3-吡咯啉,tech.85%(remainderpyrrolidine) 3-Pyrroline, tech. 85% (remainder pyrrolidine)(109-96-6)
  • 方法一:109-96-6(3-吡咯啉)一般由吡咯被锌／乙酸还原而得。也可由二烯丙胺在Schrock催化剂催化下的关环复分解反应制得，但产率较低.
  • 图谱信息:3-吡咯啉(109-96-6)质谱(MS) 3-吡咯啉(109-96-6)红外图谱(IR1) 3-吡咯啉(109-96-6)核磁图( 1 HNMR) 3-吡咯啉(109-96-6)核磁图( 13 CNMR)
  • 敏感性:Air Sensitive & Hygroscopic
  • MOL 文件:109-96-6.mol
  • 3-吡咯啉价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0577 3-吡咯啉(含吡咯烷) 3-Pyrroline (contains Pyrrolidine) 5ML 1660元 2010/06/21 132132500 3-吡咯啉 3-Pyrroline 97% 250 MG 583元 2010/06/21 132130010 3-吡咯啉 3-Pyrroline 97% 1 GR 1668元
  • Acros Organics:3-吡咯啉 3-Pyrroline, 97%(109-96-6)
  • MSDS 信息:3-Pyrroline(109-96-6).msds
  • 外观性质:3-吡咯啉（109-96-6）是无色具有胺类气味的液体，在空气中易挥发，易吸湿，易吸收二氧化碳。具有碱性和仲胺的性质，易被还原为吡咯烷。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyrroles 吡咯
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyrrolidines 吡咯烷
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyrrolines 吡咯啉

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