N-Benzyloxycarbonyl-L-alanine 苄氧羰基-L-丙氨酸

CAS 1142-20-7 MFCD00002640

化学结构图

1142-20-7
SMILES: C[C@H](NC(=O)OCc1ccccc1)C(=O)O

化学属性

Mol. FormulaC11H13NO4
Mol. Weight223.23
Density1.246
Melting Point82-84°C
TSCANo
Refractive index-14.5 ° (C=2, AcOH)
Boiling Point422.1°C at 760 mmHg

别名和识别编码

Chemical NameN-Benzyloxycarbonyl-L-alanine
CAS Number1142-20-7
Alfabeta NameBENZYLOXYCARBONYLALANINE NL[]()---
MDL NumberMFCD00002640
EC Number214-532-8
Beilstein Registry Number2056164
Synonym N-[(Benzyloxy)carbonyl]-L-alanine {LY} N-[(Benzyloxy)carbonyl]-L-alanine {} {LY} N-[(Benzyloxy)carbonyl]-L-alanine {} {} {LY} N-[(Benzyloxy)carbonyl]-L-alanine {} {} {} {LY} N-[(Benzyloxy)carbonyl]-L-alanine {} {} {} {} {LY} N-[(Benzyloxy)carbonyl]-L-alanine {} {} {} {} {} {LY} N-[(Benzyloxy)carbonyl]-L-alanine {} {} {} {} {} {} {LY} N-[(Benzyloxy)carbonyl]-L-alanine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-[(Benzyloxy)carbonyl]-L-alanine {} {} {} {} {} {} {} {} {LY} N-[(Benzyloxy)carbonyl]-L-alanine {} {} {} {} {} {} {} {} {} {LY} N-[(Benzyloxy)carbonyl]-L-alanine {} {} {} {} {} {} {} {} {} {} {LY} N-[(Benzyloxy)carbonyl]-L-alanine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-[(Benzyloxy)carbonyl]-L-alanine {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-[(Benzyloxy)carbonyl]-L-alanine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-[(Benzyloxy)carbonyl]-L-alanine {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID736104
Chemical Name Translation苄氧羰基-L-丙氨酸
Reaxys-RN2056164
InChIKeyTYRGLVWXHJRKMT-QMMMGPOBSA-N
Canonical SMILESC[C@@H](C(O)=O)NC(OCC1=CC=CC=C1)=O
InChIInChI=1S/C11H13NO4/c1-8(10(13)14)12-11(15)16-7-9-5-3-2-4-6-9/h2-6,8H,7H2,1H3,(H,12,15)(H,13,14)/t8-/m0/s1
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分类

  • {SNA} Alanine, Amino Acids & Derivatives, Chemical Biology, Chemical Synthesis, Peptide Chemistry
  • {SNA} Alanine, Amino Acid Derivatives, Chemical Biology, Chemical Synthesis, Peptide Chemistry

产品应用

  • 用于生化试剂，多肽合成。

相关文献及参考

  • Beilstein: 6,IV,2321

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S22 Do not breathe dust 不要吸入粉尘；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P352
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激

其他信息

  • 下游产品:地拉普利
  • 外观性质:白色细粉末晶体.熔点:81℃～85℃
  • Sigma Aldrich:1142-20-7(sigmaaldrich)
  • 用途一:用于生化试剂，多肽合成。
  • MSDS 信息:N-CBZ-L-Alanine(1142-20-7).msds
  • Alfa Aesar:N-苄氧羰基-L-丙胺酸,98% N-Benzyloxycarbonyl-L-alanine, 98%(1142-20-7)
  • Acros Organics:N-苄氧羰基-L-丙氨酸 N-Carbobenzyloxy-L-alanine, 98%(1142-20-7)
  • TCI Shanghai:N-苄氧羰基 -L-丙氨酸 N-Carbobenzoxy-L-alanine,>;99.0%(T)(1142-20-7)
  • MOL 文件:1142-20-7.mol
  • 苄氧羰基-L-丙氨酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0633 N-苄氧羰基 -L-丙氨酸 N-Carbobenzoxy-L-alanine 10G 278元 2014/06/02 C0633 N-苄氧羰基 -L-丙氨酸 N-Carbobenzoxy-L-alanine 25G 501元 2010/06/21 169001000 苄氧羰基-L-丙氨酸 N-Carbobenzyloxy-L-alanine 98% 100 GR 2308元
  • 图谱信息:苄氧羰基-L-丙氨酸(1142-20-7)质谱(MS) 苄氧羰基-L-丙氨酸(1142-20-7)Raman光谱 苄氧羰基-L-丙氨酸(1142-20-7)核磁图( 13 CNMR) 苄氧羰基-L-丙氨酸(1142-20-7)核磁图( 1 HNMR) 苄氧羰基-L-丙氨酸(1142-20-7)红外图谱(IR1) 苄氧羰基-L-丙氨酸(1142-20-7)红外图谱(IR2)
  • 比旋光度:-15 ° (c=2, AcOH 24 °C)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Amino Acid Derivatives 氨基酸及其衍生物
  5. Alanine - Amino Acid Derivatives
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Amino Acids 氨基酸
  4. Modified Amino Acids - Amino Acids
  5. Cbz-amino Acids
  1. Life Science 生命科学
  2. Biochemistry / Glyco-Chemistry
  3. Protected & Labeled Amino Acids

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