Z-Ser-OH N-Cbz-L-丝氨酸
CAS 1145-80-8 MFCD00002662
化学结构图
SMILES: O=C(N[C@@H](CO)C(=O)O)OCc1ccccc1
化学属性
| Mol. Formula | C11H13NO5 |
|---|---|
| Mol. Weight | 239.22 |
| Density | 1.354 |
| Melting Point | 116-119°C |
| TSCA | No |
| Refractive index | 6.1 ° (C=6, AcOH) |
| Boiling Point | 487.5°C at 760 mmHg |
别名和识别编码
| Chemical Name | Z-Ser-OH |
|---|---|
| CAS Number | 1145-80-8 |
| Alfabeta Name | CBZSERINE NL--- |
| MDL Number | MFCD00002662 |
| Synonym | Z-Ser-OH {LY} Z-Ser-OH {} {LY} Z-Ser-OH {} {} {LY} Z-Ser-OH {} {} {} {LY} Z-Ser-OH {} {} {} {} {LY} Z-Ser-OH {} {} {} {} {} {LY} Z-Ser-OH {} {} {} {} {} {} {LY} Z-Ser-OH {} {} {} {} {} {} {} {LY} Z-Ser-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Ser-OH {} {} {} {} {} {} {} {} {} {LY} Z-Ser-OH {} {} {} {} {} {} {} {} {} {} {LY} Z-Ser-OH {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Ser-OH {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Ser-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Ser-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Ser-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Ser-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Ser-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Ser-OH {} {} {} {} {} {} {} {} {} {} {} {} { |
| EC Number | 214-546-4 |
| Beilstein Registry Number | 2058314 |
| PubChem Substance ID | 87565726 |
| Reaxys-RN | 2058314 |
| Chemical Name Translation | N-Cbz-L-丝氨酸 |
| InChIKey | GNIDSOFZAKMQAO-VIFPVBQESA-N |
| LabNetwork Molecule ID | LN00173184 |
| Canonical SMILES | OC[C@@H](C(O)=O)NC(OCC1=CC=CC=C1)=O |
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分类
- Amino Acids & Derivatives
- {SNA} Amino Acid Derivatives, Chemical Biology, Chemical Synthesis, Peptide Chemistry, Serine
- Aromatics
- {SNA} Amino Acids & Derivatives, Chemical Biology, Chemical Synthesis, Peptide Chemistry, Serine
产品应用
- 用于生化试剂，多肽合成。
相关文献及参考
- For a different synthesis of racemic pyrazoloaniline, see 2-Acetamidoacrylic acid, L01649.
- Pansare, S. V.; Org. Synth. 70, 10(1992)
- Mitsunobu conversion to the ß-lactone and subsequent reaction with pyrazole is an example of a versatile route to N-protected ɑ-amino acids: Org. Synth. Coll., 9, 58 (1998) and references therein:
- Beilstein: 6,IV,2374
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
其他信息
- 比旋光度:6 ° (c=7, AcOH)
- Alfa Aesar:N-苄氧羰基-L-丝氨酸,99% N-Benzyloxycarbonyl-L-serine, 99%(1145-80-8)
- MOL 文件:1145-80-8.mol
- 外观性质:白色粉末状晶体。熔点：116～119℃
- 用途一:用于生化试剂，多肽合成。
- Sigma Aldrich:1145-80-8(sigmaaldrich)
- N-苄氧羰基-L-丝氨酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0635 N-苄氧羰基-L-丝氨酸 N-Carbobenzoxy-L-serine 5G 157元 2014/06/02 C0635 N-苄氧羰基-L-丝氨酸 N-Carbobenzoxy-L-serine 25G 616元 2010/06/21 229510250 N-苄氧羰基-L-丝氨酸 N-Carbobenzyloxy-L-serine 99+% 25 GR 977元
- 图谱信息:N-苄氧羰基-L-丝氨酸(1145-80-8)质谱(MS) N-苄氧羰基-L-丝氨酸(1145-80-8)红外图谱(IR2) N-苄氧羰基-L-丝氨酸(1145-80-8)红外图谱(IR1) N-苄氧羰基-L-丝氨酸(1145-80-8)Raman光谱 N-苄氧羰基-L-丝氨酸(1145-80-8)核磁图( 1 HNMR)
- MSDS 信息:Z-Ser-OH(1145-80-8).msds
- TCI Shanghai:N-苄氧羰基-L-丝氨酸 N-Carbobenzoxy-L-serine,>;98.0%(LC)(T)(1145-80-8)
- Acros Organics:N-羰酰苄氧基-L-丝氨酸 N-Carbobenzyloxy-L-serine, 99+%(1145-80-8)
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