Methyltriphenylarsonium iodide 甲基三苯基碘化砷

CAS 1499-33-8 MFCD00031543

化学结构图

1499-33-8
SMILES: C[As+](c1ccccc1)(c1ccccc1)c1ccccc1.[I-]

化学属性

Mol. FormulaC19H18AsI
Mol. Weight448.17
Melting Point171-175 °C
TSCAYes

别名和识别编码

Chemical NameMethyltriphenylarsonium Iodide
Synonym Methyltriphenylarsonium iodide {LY} Methyltriphenylarsonium iodide {} {LY} Methyltriphenylarsonium iodide {} {} {LY} Methyltriphenylarsonium iodide {} {} {} {LY} Methyltriphenylarsonium iodide {} {} {} {} {LY} Methyltriphenylarsonium iodide {} {} {} {} {} {LY} Methyltriphenylarsonium iodide {} {} {} {} {} {} {LY} Methyltriphenylarsonium iodide {} {} {} {} {} {} {} {LY} Methyltriphenylarsonium iodide {} {} {} {} {} {} {} {} {LY} Methyltriphenylarsonium iodide {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} Methyltriphenylarsonium iodide {} {} {} {} {} {} {} {} {} {} {LY} Methyltriphenylarsonium iodide {} {} {} {} {} {} {} {} {} {} {} {LY} Methyltriphenylarsonium iodide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyltriphenylarsonium iodide {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyltriphenylarsonium iodide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyltriphenylarsonium iodide {} {} {} {} {} {} {
MDL NumberMFCD00031543
CAS Number1499-33-8
EC Number216-108-8
Beilstein Registry Number3639838
Reaxys-RN3639838
PubChem Substance ID73911
Chemical Name Translation甲基三苯基碘化砷
InChIKeyGHLKOMSNOFJXDT-UHFFFAOYSA-M
LabNetwork Molecule IDLN01742956
InChIInChI=1S/C19H18As.HI/c1-20(17-11-5-2-6-12-17,18-13-7-3-8-14-18)19-15-9-4-10-16-19;/h2-16H,1H3;1H/q+1;/p-1
Canonical SMILESC[As+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[I-]
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 2fragments; ionic

相关文献及参考

  • Short: III/35C4
  • Arsenic analogue of Wittig salt; see Appendix 1. Review: Adv. Organomet. Chem., 20, 115 (1982). Arsonium ylides with electron-withdrawing groups in the alkylidene group are more reactive than their phosphonium counterparts. For an application in the synthesis of pentafluorophenylalkenes, by in situ generation of the pentafluorophenyl methylide, see: Synthesis, 65 (1987):
  • Short: EINECS

安全信息

Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S20/21 When using do not eat, drink or smoke 使用时，不得进食，饮水或吸烟；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Packing GroupIII
UN Number UN3465 3465 3280
Risk Statements
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
  • R50/53
Storage condition Light Sensitive
Signal word
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H301+H331
  • H331 Toxic if inhaled 吸入中毒
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P301+P310+P330
  • P301+P316
  • P304+P340
  • P304+P340+P311
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard Codes T
Hazard Class6.1
GHS Symbol

其他信息

  • Alfa Aesar:甲基三苯基碘化砷,98% Methyltriphenylarsonium iodide, 98%(1499-33-8)
  • TCI Shanghai:甲基三苯基碘化砷 Methyltriphenylarsonium Iodide,>;98.0%(T)(1499-33-8)
  • MOL 文件:1499-33-8.mol
  • 图谱信息:甲基三苯基碘化砷(1499-33-8)红外图谱(IR1) 甲基三苯基碘化砷(1499-33-8)核磁图( 13 CNMR) 甲基三苯基碘化砷(1499-33-8)核磁图( 1 HNMR) 甲基三苯基碘化砷(1499-33-8)质谱(MS) 甲基三苯基碘化砷(1499-33-8)红外图谱(IR2)
  • 甲基三苯基碘化砷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0327 甲基三苯基碘化砷 Methyltriphenylarsonium Iodide 5G 1200元 2010/05/25 A18599 甲基三苯基碘化砷, 98% Methyltriphenylarsonium iodide, 98% 5g 867元 2010/05/25 A18599 甲基三苯基碘化砷, 98% Methyltriphenylarsonium iodide, 98% 25g 3444元
  • Sigma Aldrich:1499-33-8(sigmaaldrich)
  • 敏感性:Light Sensitive

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物

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