Propachlor 毒草胺

CAS 1918-16-7 MFCD00078731

化学结构图

1918-16-7
SMILES: CC(C)N(C(=O)CCl)c1ccccc1

化学属性

Mol. FormulaC11H14ClNO
Mol. Weight212
Melting Point67-76°C
Density0.791
Flash Point100 °C
Solubility微溶于水，易溶于苯、丙酮、乙醇、甲苯、四氯化碳。

别名和识别编码

Chemical NamePropachlor
Synonym 2'-CHLORO-N-ISOPROPYL ACETANILIDE 2-CHLORO-N-ISOPROPYL-N-PHENYLACETAMIDE 2-Chlor-N-isopropyl-acetanilid 2-Chloro-N-(1-methylethyl)-N-phenylacetamide 2-Chloro-N-isopropyl-N-phenylacetamide 2-Chloro-N-isopropylacetanilide 2-chloro-N-(1-methylethyl)-N-phenylacetamide 2-chloro-N-(1-methylethyl)-N-phenylethanamide 2-chloro-N-isopropylacetamide 2-chloro-N-isopropylacetanilide 2-chloro-n-(1-methylethyl)-n-phenyl-acetamid 2-chloro-n-isopropyl-acetanilid 2-氯-N-(1-甲基乙基)-N-苯 2-氯-N-异丙基乙酰苯胺 A-CHLORO-N-ISO-PROPYLACETANILIDE ALBRASS ATLAS PROPACHLOR Acetamide, 2-chloro-N-(1-methylethyl)-N-phenyl- Acetanilide, 2-chloro-N-isopropyl- Acilid Bexton Bexton 4L CP 31393 {P
MDL NumberMFCD00078731
CAS Number1918-16-7
PubChem Substance ID4931
Beilstein Registry Number2103903
EC Number217-638-2
Chemical Name Translation毒草胺
Merck Number13,7885
Wiswesser Line NotationG1VNR&Y1&1
InChIInChI=1S/C11H14ClNO/c1-9(2)13(11(14)8-12)10-6-4-3-5-7-10/h3-7,9H,8H2,1-2H3
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分类

  • {Chemicalbook} 农药: 除草剂: 酰胺类除草剂
  • {SNA} All alphabetically sorted, Alphabetical Index of Analytical Standards, Amide, Analytical Standards, Analytical/Chromatography, Chromatography, EPA, Endocrine Disruptors (Draft), Environmental Standards, Herbicides, Method and Regulat
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; amide; 1fragment
  • {SNA} Alphabetical Index of Analytical Standards, Amide, Analytical Standards, Analytical/Chromatography, Chromatography, EPA, Endocrine Disruptors (Draft), Environmental Standards, Herbicides, Method Specific, P, PON - PT, Pesticides & Metabolites

产品应用

  • 选择性芽前除草剂。用于水稻、棉花、玉米、花生、甘蔗、豌豆、蚕豆、油菜田及苗圃中，防除一年生禾本科杂草和某些阔叶草，如稗草、马唐、狗尾草、野燕麦、苋、藜、马齿苋、牛毛草等

相关文献及参考

  • Merck: 14,7793
  • Short: EINECS
  • Short: IV/8A

安全信息

RTECSAE1575000
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P352
  • P305+P351+P338
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P333+P313
  • P337+P313
  • P337+P317
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
WGK Germany3
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes Xn;N Xn,N Xn;N,N,Xn
Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S37 Wear suitable gloves 戴适当手套；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R36 Irritating to eyes 刺激眼睛
  • R50/53
  • R22 Harmful if swallowed 吞咽有害
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
UN Number 2811 UN 2811
Storage condition 室温储存 0-6°C
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 306 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 41(7),38,1976

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 710 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85ARAE "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson
   Publications, 1976/77 revision  Volume(issue)/page/year: 2,63,1977

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
D

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 380 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   WRPCA2 World Review of Pest Control.  (London, UK)  V.1-10, 1962-71.
   Discontinued.  Volume(issue)/page/year: 9,119,1970

TYPE OF TEST            : Sperm Morphology
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 672 mg/kg/16W (Intermittent)
REFERENCE :
   EKMMA8 Eksperimentalna Meditsina i Morfologiya.  (Hemus, Blvd. Russki 6,
   Sofia, Bulgaria) V.1-    1962-  Volume(issue)/page/year: 18,35,1979

TYPE OF TEST            : Mutation test systems - not otherwise specified
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 672 mg/kg/16W (Intermittent)
REFERENCE :
   EKMMA8 Eksperimentalna Meditsina i Morfologiya.  (Hemus, Blvd. Russki 6,
   Sofia, Bulgaria) V.1-    1962-  Volume(issue)/page/year: 18,35,1979

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 10 mg/kg
REFERENCE :
   CYGEDX Cytology and Genetics (English Translation).  Translation of TGANAK.
   (Allerton Press Inc., 150 Fifth Ave., New York, NY 10011)  V.8-    1974-
   Volume(issue)/page/year: 14(6),38,1980

其他信息

  • 下游产品:丁二酸 --> 烷氧基乙醇酰胺琥珀酸单酯钠盐 --> 野麦畏 --> 羊毛防缩整理剂 W-G3 --> 表面活性剂 NPES
  • 注意事项:若溅入眼睛和皮肤，立即用清水冲洗，出现中毒症状送医院对症状治疗
  • 上游原料:氯乙酰氯 --> 2-氯丙烷 --> N-异丙基苯胺
  • 灭火剂:干粉、泡沫、砂土
  • Sigma Aldrich:1918-16-7(sigmaaldrich)
  • 急救治疗:出现中毒症状送医院对症状治疗。
  • 可燃性危险特性:燃烧产生有毒氮氧化物和氯化物气体
  • 方法二:苯胺与2-氯丙烷在130-140℃，约1MPa压力下反应4h，降温至95℃，泄压后缓慢滴加氯乙酰氯，于100℃反应3h，即制得毒草胺。原料消耗定额：苯胺530kg/t、丙烯410kg/t、盐酸520kg/t、氯乙酰氯740kg/t、氯化钙200kg/t。
  • MSDS 信息:毒草安(1918-16-7).msds
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • MOL 文件:1918-16-7.mol
  • 类别:农药
  • 方法一:苯胺与2-氯丙烷于130～140℃，1MPa压力下反应4h，制得N-异丙基苯胺；降温至95℃，泄压后缓慢滴加氯乙酰氯，于100℃反应3h，制得毒草胺。
  • 外观性质:淡黄褐色固体。
  • 毒性:65%可湿性粉剂对大鼠急性经口LD 50 为1200mg/kg；10.4%水悬液对家兔急性经皮LD 50 380mg/kg。对眼睛有刺激性。鲶鱼LC 50 为1.3mg/L。
  • 用途一:属选择性芽前除草剂
  • 用途三:选择性芽前除草剂。用于水稻、棉花、玉米、花生、甘蔗、豌豆、蚕豆、油菜田及苗圃中，防除一年生禾本科杂草和某些阔叶草，如稗草、马唐、狗尾草、野燕麦、苋、藜、马齿苋、牛毛草等。
  • 急性毒性:口服- 大鼠 LD50: 710 毫克/ 公斤; 口服- 小鼠 LD50: 290 毫克/ 公斤
  • 毒性分级:高毒
  • 杀虫剂单一组分标准液
  • 用途二:酰胺类选择性芽前除草剂，用于水稻、棉花、玉米、花生、甘蔗、油菜、豆类作物，防除一年生禾本科杂草和某些阔叶杂草，如稗草、马唐、狗尾草、野燕麦、苋、藜、马齿苋、牛毛草等。应用剂量35～50g/100m 2 。在此剂量下，药剂在土壤中持效期4～6周。
  • 110℃时蒸气为4×10-3kPa。20℃水中溶解为700mg/L，丙酮30.9%，苯50%，四氯化碳14.8%，乙醇29.0%，甲苯25.5%，常温下稳定，在酸、碱中受热易分解

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Method Specific - Analytical Standards
  4. EPA - Method Specific
  5. Endocrine Disruptors (Draft) - EPA
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. P - Alphabetic
  5. PON - PT - P
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. P - Alphabetic
  5. PON - PT - P

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