Triallat 野麦畏

CAS 2303-17-5 MFCD00078730

化学结构图

2303-17-5
SMILES: CC(C)N(C(=O)SCC(Cl)=C(Cl)Cl)C(C)C

化学属性

Mol. FormulaC10H16Cl3NOS
Mol. Weight304.68
Melting Point29-30°C
Boiling Point148-149°C
Density1.273
Solubility微溶于水，溶于乙醚、丙酮、苯。
Flash Point2 °C
Refractive index1.5440

别名和识别编码

Chemical NameTriallat
Synonym S-(2,3,3-TRICHLOROALLYL)DIISOPROPYL THIOCARBAMATE {Chemicalbook} S-(2,3,3-trichloro-2-propenyl) bis(1-methylethyl)carbamothioate S-2,3,3-Trichlorallyl-diisopropylthiocarbamat S-2,3,3-Trichlorallyldiisopropylthiocarbamat Bis(isopropyl)-carbamothioic acid S-(2,3,3-trichloro-allyl) ester, 2,3,3-trichloro-2-propene-1-thiol diisopropylcarbamate 野麦畏 CP 23 Carbamothioic acid, bis(1-methylethyl)-, S-(2,3,3-trichloro-2-propenyl) ester Carbamic acid, diisopropylthio-, S-(2,3,3-trichloroallyl) ester tri-allate 2,3,3-trichloro-2-propene-1-thiodiisopropylcarbamate triallate tri allate Dipthal 2,3,3-Trichloroallyl d {uni_hambu S-2,3,3-三氯烯丙基-N-二异丙基硫羟氨基甲酸酯 2,3,3-trichloroallyldiisopropylthiocarbamate { 2,3,3-Trichlorallyl-N,N-(diisopropyl)-thiocarbamat 2-Propene-1-thiol, 2,3,3-trichloro-, diisopropylcarbamate S-(2,3,3-trichloro-2-propenyl)bis( 2,3,3-Trichloroallyl diisopropylthiocarbamate S-(2,3,3-三氯-2-丙烯基)双(1-甲基乙基)硫代氨基甲酸酯 Diisopropyltrichloroallylthiocarbamate 三氯烯丹 S-2,3,3-trichloroallyl iso S-(2,3,3-Trichloro-2-propenyl) bis(1-methylethyl)carbamothioate Triallate {C 2,3,3-TRICHLOROALLYL-N,N-DIISOPROPYL-THIOLCARBAMATE S-(2,3,3-三氯烯丙基)-N,N-二异丙基硫代氨基甲酸酯 2,3,3-Trichloro-2-propene-1-thiol diisopropylcarbamate; S-(2,3,3-Trichloro-2-propenyl) bis(1-methylethyl)carbamothioate Far-Go 2,3,3-Trichloroallyl N,N-diisopropylthiocarbamate 野燕畏 S-2,3,3-Trichloroallyl diis 燕麦畏 三氯烯丹,燕麦畏,野燕畏,S-2,3,3-三氯烯丙基二异丙基硫代氨基甲酸酯,S-(2,3,3-三氯-2-丙烯基)双(1-甲基乙基)硫代氨基甲酸酯 {hazard_c
MDL NumberMFCD00078730
PubChem Substance ID5543
Beilstein Registry Number1875853
CAS Number2303-17-5
EC Number218-962-7
Chemical Name Translation野麦畏
Merck Number13,9669
Wiswesser Line NotationGYGUYG1SVNY1&1&Y1&1
InChIInChI=1S/C10H16Cl3NOS/c1-6(2)14(7(3)4)10(15)16-5-8(11)9(12)13/h6-7H,5H2,1-4H3
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分类

  • {uni_hamburg} no charge; thioester; 1fragment
  • {SNA} Alphabetic, Analytical Standards,
  • Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Herbicides, Pesticides & Metabolites, Q-Z, T, TP - TZ, Thiocarbamates
  • {SNA} All Herbicide Standards, Analytical Standards, Q-Z, T-Z, Thiocarbamates, 农残和代谢标准品, 分析/色谱, 按照字母排序, 灭草剂
  • {SNA} All alphabetically sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography,
  • {Chemicalbook} 农药: 除草剂: 氨基甲酸酯类除草剂

产品应用

  • 该品是防除野麦类的选择性土壤处理剂，适用于小麦、大麦、青稞、油菜、豌豆、蚕豆、亚麻、甜菜、大豆等作物田防除野燕麦。

相关文献及参考

  • Short: IV/20C
  • Short: EINECS
  • Short: IV/8A
  • Merck:13,9669

安全信息

RTECSEZ8575000
GHS Symbol
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H302 Harmful if swallowed 吞食有害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Hazard Codes Xn;N Xn;N,N,Xn,F Xn,N
WGK Germany3
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Signal word Warning
Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S37 Wear suitable gloves 戴适当手套；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R50/53
  • R48/22
  • R22 Harmful if swallowed 吞咽有害
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R11 Highly flammable 非常易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36 Irritating to eyes 刺激眼睛
UN Number 3077 UN 3077
Storage condition APPROX 4°C 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 930 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - excitement
   Behavioral - muscle contraction or spasticity
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 33(7),37,1968

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 2225 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   28ZEAL "Pesticide Index," Frear, E.H., ed., State College, PA, College
   Science Pub., 1969  Volume(issue)/page/year: 5,226,1976

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : >20 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd,
   eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year:
   A403,1984

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - cat
DOSE/DURATION           : 400 mg/m3/4H
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - food intake (animal)
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 33(7),37,1968

TYPE OF TEST            : LDLo - Lowest pu

{haz

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 20 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 85,45,1981

{h

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   JAFCAU Journal of Agricultural and Food

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 40 ppm
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB84-138973

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 nmol/plate
REFERENCE :
   BCPCA6 Biochemical Pharmacology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.1-    1958-  Volume(issue)/page/year:
   32,3739,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 4800 ug/plate
REFERENCE :
   CBINA8 Chemico-Biological Interactions.  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1969-  Volume(issue)/page/year:
   22,297,1978

TYPE OF TEST            : DNA inhibition
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 100 mg/L
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   45,101,1980

TYPE OF TEST

TY

其他信息

  • 上游原料:二硫化碳 --> 二异丙胺 --> 羰基硫 --> 毒草安 --> 四氯丙烯
  • 油状液体，对紫外光稳定。
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 用途二:选择性土壤处理剂，对防除野燕麦有特效。杂草芽鞘或第一片子叶吸收药剂后，影响细胞的蛋白质合成和有丝分裂，抑制细胞伸长，使杂草未出土就死亡。可用于大麦和小麦田除防野燕麦等杂草，也可用于油菜、豌豆、亚麻、甜菜、青梨和大豆等作物，用量为8～16g有效成分/100m 2 ，与土壤掺和施用。
  • 毒性:大鼠急性经口LD 50 为1675～2165mg/kg（1800mg/kg)，家兔急性经皮LD 50 为2225～4050mg/kg。大鼠喂养2年无作用剂量200mg/kg。对兔眼睛有轻度刺激作用，对皮肤有中等刺激。在动物体内蓄积作用中等。Ames试验阴性。国外报道致突变Ames试验 （对TA 1535 、TA 98 、TA 100}）有轻度诱变作用，高剂量组（1/5 LD 50 ）可导致小鼠骨髓细胞微核率增高。在试验条件下对大鼠和家兔无致畸作用，无致癌作用。虹鳟鱼LC 50 为1.2mg/L (96h)，鹌鹑急性经口LD 50 为2251mg/kg。
  • 类别:农药
  • Sigma Aldrich:2303-17-5(sigmaaldrich)
  • 毒性分级:中毒
  • 急救治疗:无特效解毒药，对症治疗。 不能催吐。
  • 用途一:适用于小麦、青稞、油菜、豌豆、亚麻、甜菜、大豆等农作物田防除野燕麦
  • MSDS 信息:野麦畏(2303-17-5).msds
  • 外观性质:琥珀色油状液体。
  • 方法二:将二异丙胺加入氢氧化钠溶液中，搅拌冷却，于0-5℃通入二硫化碳，直至通完计算量。将1,1',2,3-四氯丙烯加入反应液中，在0-65℃反应6h。冷却静置分层。上层为母液，下层为粗产品。将粗产品减压蒸馏，蒸出来反应的四氯丙烯等低沸物，剩下的琥珀稠油状液即为野麦畏。原料消耗定额：二异丙胺（96%）300kg/t、四氯丙烯（80%）600kg/t、氯气600kg/t。
  • 灭火剂:干粉、泡沫、砂土
  • 方法一:将3g氢氧化钠溶于20mL水中，在室温下与5.5g (98%)二异丙胺混合，将反应液冷却至0～5℃，在搅拌下通入氧硫化碳气，约吸收3g左右，有大量结晶析出，继续保温反应，在搅拌下将18g (70%)1，1，2，3-四氯丙烯投入反应液中，在0～65℃继续反应6h，冷却至室温，静置分层，将下层粗产品减压蒸馏，蒸出低沸物后，剩下琥珀色黏稠状液体即为产品。
  • 可燃性危险特性:燃烧产生有毒氮氧化物、氯化物和硫氧化物气体
  • 急性毒性:口服- 大鼠 LD50: 800 毫克 / 公斤; 口服- 小鼠 LD50: 930 毫克/ 公斤
  • 用途三:该品是防除野麦类的选择性土壤处理剂，适用于小麦、大麦、青稞、油菜、豌豆、蚕豆、亚麻、甜菜、大豆等作物田防除野燕麦。
  • MOL 文件:2303-17-5.mol
  • 中毒症状:对皮肤和眼睛有刺激性。摄入量大时，对胆碱酯酶有抑制作用。
  • 注意事项:[1]野麦畏有挥发性，需随施随混土。[2]种子与药接触会产生药害

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Alpha sort - Pesticides & Metabolites
  7. Q-Z - Alpha sort
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. T - Alphabetic
  5. TP - TZ - T

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