2,6-Bis(chloromethyl)pyridine 2,6-双(氯甲基)吡啶

CAS 3099-28-3 MFCD00142844

化学结构图

3099-28-3
SMILES: ClCc1cccc(CCl)n1

化学属性

Mol. FormulaC7H7Cl2N
Mol. Weight176.04 g/mol
Melting Point73.0 to 77.0 deg-C
Density1.422
Boiling Point110°C/3mmHg(lit.)

别名和识别编码

Chemical Name2,6-Bis(chloromethyl)pyridine
Synonym ,-Dichloro-2,6-lutidine 2,6-BIS(CHLOROMETHYL)PYRIDINE 98+% 2,6-Bis(chloromethyl)pyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00142844
PubChem Substance ID87564367
Beilstein Registry Number116355
CAS Number3099-28-3
Reaxys-RN116355
EC Number250-023-7
Chemical Name Translation2,6-双(氯甲基)吡啶
LabNetwork Molecule IDLN01740497
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分类

  • {SNA} Building Blocks, C7, C7 to C8, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Pyridines
  • Building Blocks, C7 to C18, C7 to C8, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Pyridines

相关文献及参考

  • Beil. 20 ,IV,2780
  • FT-IR 2 (3), 3726:B / Structure Index 1 , 395:E:7

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险

其他信息

  • 方法一:用2,6-二甲基吡啶在紫外线催化下以氯气氯化制得。
  • 上游原料:2,6-二甲基吡啶
  • MOL 文件:3099-28-3.mol
  • TCI Shanghai:2,6-二氯甲基吡啶 2,6-Bis(chloromethyl)pyridine,>;98.0%(GC)(3099-28-3)
  • Sigma Aldrich:3099-28-3(sigmaaldrich)
  • 用途一:血脉宁（安吉宁）的中间体。
  • 图谱信息:2,6-双（氯甲基）吡啶(3099-28-3)核磁图( 1 HNMR) 2,6-双（氯甲基）吡啶(3099-28-3)质谱(MS) 2,6-双（氯甲基）吡啶(3099-28-3)红外图谱(IR2) 2,6-双（氯甲基）吡啶(3099-28-3)红外图谱(IR1) 2,6-双（氯甲基）吡啶(3099-28-3)核磁图( 13 CNMR)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Halogenated Heterocycles 卤代杂环
  5. Pyridines - Halogenated Heterocycles
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Halogenated Heterocycles 卤代杂环
  5. Pyridines - Halogenated Heterocycles
  6. C7 to C18 - Pyridines
  1. C7 to C8 - Pyridines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyridines 吡啶

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