Tris(2-methylpropyl)phosphine Tri-i-butylphosphine,
CAS 4125-25-1 MFCD00015049
化学结构图
SMILES: CC(C)CP(CC(C)C)CC(C)C
化学属性
| Refractive index | n20/D 1.451(lit.) |
|---|---|
| Density | 0.811 g/mL at 25 °C(lit.) |
| Mol. Formula | (i-C4H9)3P |
| Mol. Weight | 202 |
| Appearance | colorless to light yellow liq. |
| Stability | air sensitive |
| Boiling Point | 85°C/7mm |
别名和识别编码
| Chemical Name | min. 93% |
|---|---|
| Synonym | 三(2-甲基丙基)膦 三异丁基膦烷 |
| PubChem Substance ID | 107228 |
| EC Number | 223-934-2 |
| Beilstein Registry Number | 1738664 |
| Chemical Name Translation | Tri-i-butylphosphine, |
| InChIKey | DAGQYUCAQQEEJD-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN02178370 |
| InChI | InChI=1S/C12H27P/c1-10(2)7-13(8-11(3)4)9-12(5)6/h10-12H,7-9H2,1-6H3 |
| MDL Number | MFCD00015049 |
| CAS Number | 4125-25-1 |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H332 Harmful if inhaled 吸入有害
- H302 Harmful if swallowed 吞食有害
- H312 Harmful in contact with skin 皮肤接触有害
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
- P222 Do not allow contact with air. 不要与空气接触。
- P422 Store contents under… 存储目录在…之下。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P231 Handle under inert gas. 在惰性气体中操作。
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- R17 Spontaneously flammable in air 在空气中能够自燃
- R34 Causes burns 会导致灼伤
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