2-Bromo-5-nitropyridine 2-溴-5-硝基吡啶

CAS 4487-59-6 MFCD00006222

化学结构图

4487-59-6
SMILES: O=[N+]([O-])c1ccc(Br)nc1

化学属性

Mol. FormulaC5H3BrN2O2
Mol. Weight202.99
Boiling Point289.3°C at 760 mmHg
Melting Point139-141°C
Density1.834
TSCANo
Flash Point145-147°C/10mm

别名和识别编码

Chemical Name2-Bromo-5-nitropyridine
CAS Number4487-59-6
Alfabeta NameBROMONITROPYRIDINE 25---
MDL NumberMFCD00006222
Synonym 2-Bromo-5-nitropyridine {LY} 2-Bromo-5-nitropyridine {} {LY} 2-Bromo-5-nitropyridine {} {} {LY} 2-Bromo-5-nitropyridine {} {} {} {LY} 2-Bromo-5-nitropyridine {} {} {} {} {LY} 2-Bromo-5-nitropyridine {} {} {} {} {} {LY} 2-Bromo-5-nitropyridine {} {} {} {} {} {} {LY} 2-Bromo-5-nitropyridine {} {} {} {} {} {} {} {LY} 2-Bromo-5-nitropyridine {} {} {} {} {} {} {} {} {LY} 2-Bromo-5-nitropyridine {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-5-nitropyridine {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-5-nitropyridine {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-5-nitropyridine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-5-nitropyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-5-nitropyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-5-nitropyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-5-nitr
EC Number224-777-2
Beilstein Registry Number120901
PubChem Substance ID78240
Reaxys-RN120901
Chemical Name Translation2-溴-5-硝基吡啶
InChIKeyHUUFTVUBFFESEN-UHFFFAOYSA-N
LabNetwork Molecule IDLN00008169
InChIInChI=1S/C5H3BrN2O2/c6-5-2-1-4(3-7-5)8(9)10/h1-3H
Canonical SMILESBrC1=NC=C([N+]([O-])=O)C=C1
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分类

  • Bases & Related Reagents
  • Nucleotides
  • {SNA} Building Blocks, C5, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Pyridines

相关文献及参考

  • Beilstein:20(5)5,455

安全信息

Warnings IRRITANT, IRRITANT-HARMFUL
Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P312+P330
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H301 Toxic if swallowed 吞食有毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes 6.1 Xn Xn,Xi
UN Number 2811 UN 2811 6.1/PG 3
Packing GroupIII
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature

其他信息

  • Hazard Note:Irritant/Keep Cold
  • 下游产品:2-溴-5-羟基吡啶 --> 5-氨基吡啶-2-磺酸 --> 6-氨甲基-3-氨基吡啶 --> 3-氨基-6-溴吡啶 --> 5-乙酰氨基-2-溴砒啶
  • Sigma Aldrich:4487-59-6(sigmaaldrich)
  • 图谱信息:2-溴-5-硝基吡啶(4487-59-6)核磁图( 1 HNMR)
  • Alfa Aesar:2-溴-5-硝基吡啶,98+% 2-Bromo-5-nitropyridine, 98+%(4487-59-6)
  • 2-溴-5-硝基吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xp300049 2-溴-5-硝基吡啶 5g 340元 2011/04/16 B2321 2-溴-5-硝基吡啶 2-Bromo-5-nitropyridine 5G 691元 2011/04/16 B2321 2-溴-5-硝基吡啶 2-Bromo-5-nitropyridine 1G 233元
  • 检测方法:HPLC
  • MOL 文件:4487-59-6.mol
  • TCI Shanghai:2-溴-5-硝基吡啶 2-Bromo-5-nitropyridine,>;98.0%(GC)(4487-59-6)
  • Acros Organics:2-Bromo-5-nitropyridine, 98%(4487-59-6)
  • 上游原料:乙醇 --> 三溴化磷 --> 氧溴化磷 --> 2-羟基-5-硝基吡啶

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Halogenated Heterocycles 卤代杂环
  5. Pyridines - Halogenated Heterocycles
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Halogenated Heterocycles 卤代杂环
  5. Pyridazines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyridines 吡啶

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