Allyl Ethyl Sulfide 烯丙基乙硫醚

CAS 5296-62-8 MFCD00026979

化学结构图

5296-62-8
SMILES: CCSCC=C

化学属性

Mol. FormulaC5H10S
Mol. Weight102
Density0.868
Refractive index1.4680
Flash Point18°(64°F)
TSCANo
Boiling Point115-116°

别名和识别编码

Chemical NameAllyl Ethyl Sulfide
Synonym allyl ethyl sulfide ethyl allyl sulfide ethyl-allyl sulfide Allylethylsulfid Allyl ethyl sulphide 3-Ethylthio-1-propene
MDL NumberMFCD00026979
CAS Number5296-62-8
Beilstein Registry Number1736876
Chemical Name Translation烯丙基乙硫醚
InChIKeyNOJXPGXFDASWEI-UHFFFAOYSA-N
LabNetwork Molecule IDLN02143770
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分类

  • {uni_hamburg} no charge; sulfide; 1fragment

相关文献及参考

  • Short: IV/18B Title: Viscosity of Pure Organic Liquids and Binary Liquid Mixtures: Pure Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/18B Year: 2001 Keyword: organic compounds; viscosity; liquids; mixtures Internet Resource: DOI:10.1007/b68240 RefComment: VII, 409 pages.
  • Short: IV/20A Title: Vapor Pressure and Antoine Coefficients for Hydrocarbons and Sulfur-, Selenium-, Tellurium-, and Halogen-Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20A Year: 1999 Keyword: organic compounds; vapor pressure ISBN: 3-540-64735-X ISBN: 978-3-540-64735-5 Internet Resource: DOI:10.1007/b71086 RefComment: VIII, 373 pages.
  • The lithiated derivative can react with electrophiles at either the ɑ- or - postion. It was found that conversion of the organolithium to an organotitanium reagent (by reaction with Ti(O-iPr)4), followed by reaction with e.g. cyclohexanecarboxaldehyde resulted in regioselective reaction at the ɑ-position to give the corresonding hydroxy sulfide: Bull. Chem. Soc. Jpn., 57, 2781 (1984). For review of allylic and benzylic carbanions substituted by heteroatoms, see: Org. React., 27, 1 (1982).

安全信息

Packing GroupII
UN Number UN1993
Risk Statements
  • R11 Highly flammable 非常易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S37 Wear suitable gloves 戴适当手套；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；

系列性分类

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