Trimethylarsine 三甲基胂

CAS 593-88-4 MFCD00014838

化学结构图

593-88-4
SMILES: C[As](C)C

化学属性

Mol. FormulaC3H9As
Mol. Weight120.03
Density1.124
Flash Point100°F
Appearance colorless liq.
Stabilityair sensitive
Boiling Point51 °C at 760 mmHg
Melting Point-87.3 °C

别名和识别编码

Chemical NameTrimethylarsine
Synonym Trimethylarsane {LY} Trimethylarsane {} {LY} Trimethylarsane {} {} {LY} Trimethylarsane {} {} {} {LY} Trimethylarsane {} {} {} {} {LY} Trimethylarsane {} {} {} {} {} {LY} Trimethylarsane {} {} {} {} {} {} {LY} Trimethylarsane {} {} {} {} {} {} {} {LY} Trimethylarsane {} {} {} {} {} {} {} {} {LY} Trimethylarsane {} {} {} {} {} {} {} {} {} {LY} Trimethylarsane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethylarsane {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethylarsane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethylarsane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethylarsane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethylarsane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethylarsane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethylarsane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimet
EC Number209-815-8
Chemical Name Translation三甲基胂
Beilstein Registry Number1730780
PubChem Substance ID68978
InChIInChI=1S/C3H9As/c1-4(2)3/h1-3H3
MDL NumberMFCD00014838
CAS Number593-88-4
Canonical SMILESC[As](C)C
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分类

  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: II/25C Title: Structure Data Of Free Polyatomic Molecules: Molecules containing Three or Four Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25C Year: 2001 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-66774-1 ISBN: 978-3-540-66774-2 Internet Resource: DOI:10.1007/b71431 RefComment: VIII, 481 pages. Hardcover Abstract: This volume contains data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc.) of free polyatomic molecules including free radicals and molecular ions. This survey on structure data is made of four subvolume, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this third subvolume, the structure of molecules containing three for four carbon atoms are listed.
  • Short: II/4 Title: Molecular Constants from Microwave Spectroscopy Author: Starck, B. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/4 Page: 1-225 Year: 1967 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-03896-5 ISBN: 978-3-540-03896-2 Internet Resource: DOI:10.1007/b19949 RefComment: 67 figs., X
  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Y

安全信息

WGK Germany3
RTECSCH8800000 
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 20500 ppm/4H
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - tremor
   Behavioral - ataxia
REFERENCE :
   TOXID9 Toxicologist.  (Soc. of Toxicology, Inc., 475 Wolf Ledge Parkway,
   Akron, OH 44311) V.1-    1981-  Volume(issue)/page/year: 3,24,1983

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 7870 mg/kg
TOXIC EFFECTS :
   Blood - other changes
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   14,399,1990

Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
  • H301 Toxic if swallowed 吞食有毒
  • H331 Toxic if inhaled 吸入中毒
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P231+P232
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P303+P361+P353
  • P304+P340
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P370+P378
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P402+P404
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Storage condition

系列性分类

  1. CVD & ALD Precursors
  2. Arsenic
  1. Metal Alkyls
  2. Arsenic
  1. Ligands
  2. Arsenic

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