1,2-Dimethylpropylamine 3-甲基-2-丁胺

CAS 598-74-3 MFCD00008081

化学结构图

598-74-3
SMILES: CC(C)C(C)N

化学属性

Mol. FormulaC5H13N
Mol. Weight87
Refractive indexn20/D 1.4055(lit.)
Boiling Point84-87 °C(lit.)
Density0.757 g/mL at 25 °C(lit.)
Melting Point-50 °C(lit.)
Flash Point-27°C(lit.)
TSCAYes

别名和识别编码

Chemical Name1,2-Dimethylpropylamine
Synonym (+/-)-3-Methyl-2-butylamine 1,2-Dimethylpropanamine 1,2-dimethylpropylamine (±)-3-Methyl-2-butylamine,98+% iso-Amylamine 3-Methyl-2-butylamin 2-AMINO-3-METHYLBUTANE 1,2-dimethyl-propylamine 3-methyl-2-butanamin 1,2-二甲基丙胺 2-Butanamine, 3-methyl- (+/-)-2-AMINO-3-METHYLBUTANE (±)-3-Methyl-2-butylamine (n)-3-methyl-2-butylamine Propylamine, 1,2-dimethyl- 1,2-Dimethylpropylamine (±)-1,2-Dimethylpropylamine 2-Amino-3-methylbutane; 3-Methyl-2-butylamine 3-Methylbutane-2-amine 3-Methyl-2-butanamine 3-甲基-2-丁胺 1,2-甲基丙胺 (+/-)-3-METHYL-2-BUTYLAMINE (±)-3-甲基-丁胺,98+% (+/-)-1,2-DIMETHYLPROPYLAMINE, 98+% (±)-2-Amino-3-methylbutane 3-Methyl-2-aminobutane 1,2-DIMETHYLPROPYLAMINE 1,2-dimethyl-propylamin (±)-3-甲基-丁胺 3-Amino-2-methylbutane 2-Amino-3-methylbutane 3-METHYL-2-BUTANAMINE (±)-1,2-dimethyl-propylamine
MDL NumberMFCD00008081
CAS Number598-74-3
PubChem Substance ID24851417
EC Number209-949-7
Beilstein Registry Number0635656
Chemical Name Translation3-甲基-2-丁胺
Reaxys-RN635656
InChIKeyJOZZAIIGWFLONA-UHFFFAOYSA-N
LabNetwork Molecule IDLN00243724
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分类

  • {SNA} Amines, Building Blocks, C2 to C5, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; racemate; 1fragment

产品应用

  • 有机合成原料,用于合成杀虫剂,也可用作试剂。还用作矿物浮选剂,汽油抗震剂、聚合催化剂和稳定剂等。

相关文献及参考

  • Short: EINECS
  • Short: III/38B
  • Beilstein:4,179

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H312 Harmful in contact with skin 皮肤接触有害
  • H302 Harmful if swallowed 吞食有害
  • H302+H312
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSUI1100000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338+P310
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P304+P340
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P403+P235
  • P301+P330+P331
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P304+P340+P310
  • P241+P242+P243
  • P303+P361+P353+P310+P363
  • P405 Store locked up. 上锁保管。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
Signal word Danger
Packing GroupII
UN Number 3286 UN2733 UN 3286 3/PG 2 2733
Risk Statements
  • R11 Highly flammable 非常易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R34 Causes burns 会导致灼伤
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
Storage condition RT Air Sensitive
Hazard Codes F,C F;C
Hazard Class3/8
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 810 uL/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Gastrointestinal - changes in structure or function of salivary glands
   Skin and Appendages - dermatitis, other (after systemic exposure)
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0536386

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 510 uL/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Behavioral - tremor
   Gastrointestinal - changes in structure or function of salivary glands
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0536386

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 279 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - ataxia
   Lungs, Thorax, or Respiration - respiratory stimulation
REFERENCE :
   JJPAAZ Japanese Journal of Pharmacology.  (Japanese Pharmacological Soc.,
   c/o Dept. of Pharmacology, Faculty of Medicine, Kyoto Univ., Sakyo-ku, Kyoto
   606, Japan)  V.1-    1951-  Volume(issue)/page/year: 17,475,1967

其他信息

  • 储运特性:库房通风低温干燥
  • 毒性分级:高毒
  • 类别:腐蚀物品
  • TCI Shanghai:1,2-二甲基丙胺 1,2-Dimethylpropylamine,>;98.0%(GC)(T)(598-74-3)
  • 可燃性危险特性:易燃; 受热产生有毒氮氧化物烟雾
  • 用途一:有机合成原料,用于合成杀虫剂,也可用作试剂。还用作矿物浮选剂,汽油抗震剂、聚合催化剂和稳定剂等。
  • MOL 文件:598-74-3.mol
  • Alfa Aesar:(±)-3-甲基-丁胺,98+% (+/-)-3-Methyl-2-butylamine, 98+%(598-74-3)
  • 急性毒性:腹腔-小鼠LD50: 279 毫克/公斤
  • 1,2-二甲基丙胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D1770 1,2-二甲基丙胺 1,2-Dimethylpropylamine 25ML 396元 2011/04/16 D1770 1,2-二甲基丙胺 1,2-Dimethylpropylamine 500ML 3510元 2010/05/25 L02948 (±)-3-甲基-丁胺,98+% (±)-2-Amino-3-methylbutane, 98+% 25g 382元
  • MSDS 信息:2-Amino-3-methylbutane(598-74-3).msds
  • Sigma Aldrich:598-74-3(sigmaaldrich)
  • 灭火剂:干粉、泡沫、砂土、二氧化碳
  • 图谱信息:1,2-二甲基丙胺(598-74-3)质谱(MS) 1,2-二甲基丙胺(598-74-3)红外图谱(IR1) 1,2-二甲基丙胺(598-74-3)核磁图( 1 HNMR) 1,2-二甲基丙胺(598-74-3)核磁图( 13 CNMR)

系列性分类


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