Fentin acetate 三苯基乙酸锡

CAS 900-95-8 MFCD00014977

化学结构图

900-95-8
SMILES: CC(=O)O[Sn](c1ccccc1)(c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC₂₀H₁₈O₂Sn
Mol. Weight409.07
TSCAYes
Melting Point>118ºC (dec.)
Solubility28 MG/L (20 ºC)
Density1.55
Boiling Point-
Flash Point-

别名和识别编码

Chemical NameTriphenyltin Acetate
Synonym (acetyloxy)triphenyl-Stannane (acetyloxy)triphenylsta Acetate de triphenyl-etain Acetatotriphenylstannane Acetoxy-triphenyl-stannan Acetoxy-triphenylstannane Acetoxytriphenylstannane; Triphenylacetoxytin; Triphenyltin acetate; TPTA Acetyloxytriphenylz BATASAN(R) BRESTAN Batasan Betafen Brestan Brestan 60 Brestanid ENT 25208 F Fenolovo acetate Fentin acetaat Fentin acetat Fentin acetate Fentine acetate HOE-2824 Liromatin OMS 1020 PHENTINOACETATE Phentin acetate Phentinoacetate SUZU SUZU(R) Stannane, acetoxytriphenyl- TPTA {
Beilstein Registry Number4146107
PubChem Substance ID16682804
CAS Number900-95-8
EC Number212-984-0
MDL Number-
Merck Number14,9745
Chemical Name Translation三苯基乙酸锡
Wiswesser Line Notation1VO-SN-R&R&R
InChIInChI=1S/3C6H5.C2H4O2.Sn/c3*1-2-4-6-5-3-1;1-2(3)4;/h3*1-5H;1H3,(H,3,4);/q;;;;+1/p-1
Canonical SMILES-
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分类

  • {SNA} 2000/60/EC, Additional Standards, Algicides, Analytical Standards, Baby Food Directives 13/2003 EC & 14/2003 EC, E-G, European Community: ISO, DIN and DL 152, Food and Cosmetic Component Standards, Fungicides, Method and Regulation Specific, Molluscicides, Organotins, Others, Standards for Personal Care and Cosmetic Products, neats, prohibited substances (EU-REGULATION No 1223/2009), 农残和代谢标准品, 农残标准品, 分析/色谱, 按照字母排序
  • {Chemicalbook} 农药: 杀菌剂: 化学保护剂
  • {SNA} 2000/60/EC, Algicides, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography,

相关文献及参考

  • Short: EINECS
  • Short: IV/8A
  • Merck: 14,9745

安全信息

Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P203
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P301+P316
  • P302+P352
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P354+P338
  • P307+P311
  • P308+P311
  • P308+P313
  • P308+P316
  • P309+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P316
  • P317
  • P318
  • P319
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P333+P313
  • P333+P317
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P361+P364
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSWH6650000
GHS Symbol
Signal word Danger
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H301+H311
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H330 Fatal if inhaled 吸入致命
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
  • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
  • H371 May cause damage to organs 可能导致器官损伤
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Hazard Codes T+,N T+;N,N,T+ T+;N
WGK Germany3
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
UN Number 3146 UN3146
Risk Statements
  • R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R48/23
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R26 Very toxic by inhalation 吸入极毒
  • R50/53
Packing GroupIII
Hazard Class6.1
Storage condition 4°C APPROX 4°C
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 132 gm/kg/78W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Liver - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-159

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 30 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85DPAN "Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel,"
   Perkow, W., Berlin, Verlag Paul

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION

{

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 21 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GYAV "Pflanzenschutz-und Schaedlingsbekaempfungsmittel: Abriss einer
   Toxikologie und Therapie von Vergiftungen," 2nd ed., Klimmer, O.R.,
   Hattingen, Fed. Rep. Ger., Hundt-Verlag, 1971  Volume(issue)/page/year:
   -,127,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 81 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
REFERENCE :
   BJIMAG British Journal of Industrial Medicine.  (British Medical Journal,
   Box 560B, Kennebunkport, ME 04046)  V.1-    1944-  Volume(issue)/page/year:
   23,222,1966

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 18 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, M

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 60 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 300,5,1993

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 380 mg/kg
SEX/DURATION            : male 19 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
REFERENCE :
   JEENAI Journal of Economic Entomology.  (Entomological Soc. of America, 4603
   Calvert Rd., College Park, MD 20740)  V.1-    1908- Volume(issue)/page/year:
   61,32,1968

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 50 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   BECTA6 Bulletin of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   07094)  V.1-    1966-  Volume(issue)/page/year: 24,936,1980

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 54 mg/kg
SEX/DURATION            : female 7-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - weaning or lactation index (e.g., #
   alive at weaning per # alive at day 4)
   Reproductive - Effects on Newborn - behavioral
REFERENCE :
   NTOTDY Neurobehavioral Toxicology and Teratology.  (Fayetteville, NY) V.3-8,
   1981-86.  For publisher information, see NETEEC. Volume(issue)/page/year:
   4,247,1982

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 99 mg/kg
SEX/DURATION            : female 7-17 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-i

其他信息

  • Sigma Aldrich:900-95-8(sigmaaldrich)
  • 图谱信息:三苯基锡醋酸盐(900-95-8)质谱(MS) 三苯基锡醋酸盐(900-95-8)红外图谱(IR1) 三苯基锡醋酸盐(900-95-8)红外图谱(IR2)
  • MSDS 信息:乙酰氧基三苯基锡(900-95-8).msds
  • MOL 文件:900-95-8.mol
  • Alfa Aesar:Triphenyltin acetate(900-95-8)
  • 上游原料:氢氧化钠 --> 溴苯 --> 四氯化锡 --> 三苯基氯化锡 --> 三苯基氢氧化锡
  • 用途三:防治甜菜褐斑病、马铃薯晚疫病、大豆炭疽病、黑点病、褐纹病、紫斑病。对水稻稻瘟病、稻曲病、条斑病也有较好防效。对洋葱黑斑病、芹菜叶枯病、菜豆炭疽病、咖啡的生尾孢病也都有很好的防效。特别对福寿螺、藻类、水蜗牛有着特殊防效。
  • 急性毒性:口服-大鼠 LD50: 125 毫克/公斤; 口服-小鼠 LD50: 81 毫克/公斤
  • 中毒症状:属剧烈神经毒物。头痛，头晕，多汗重者：恶心呕吐，大汗淋漓，排尿困难，抽搐，精神错乱，昏迷，呼吸困难等。
  • TSCA:Yes
  • 灭火剂:砂土、干粉、泡沫
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 毒性:大鼠急性经口LD 50 为125mg/kg，大鼠急性经皮LD 50 为500mg/kg。对黏膜有刺激性。对野鸡LC 50 约580mg/L (8d)，蜜蜂安全。
  • 类别:农药
  • 急救治疗:[1]误服者立即催吐，洗胃、导泻。 [2]无特殊解毒剂，预防治疗，防止脑水肿发生。 [3]严禁大量输液。 注意：在我国无登记产品
  • 用途二:保护性杀菌剂，无内吸作用。主要用于防治马铃薯晚疫病，甜菜褐斑病，大豆炭疽病、褐纹病、紫斑病，水稻稻瘟病、条斑 病，胡麻叶枯病，洋葱黑斑病，芹菜叶枯病，菜豆炭疽病等。用量3～6g/100m 2 。除杀菌外，也可用于防治水田中的藻类和水蜗牛。用于甜菜、大豆，还有增糖、增产的作用。用药4周后始可食用或喂饲牲畜。
  • 三苯基锡醋酸盐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 71178 Triphenyltin acetate 50g 722元 2010/05/25 71178 Triphenyltin acetate 10g 202元
  • 毒性分级:高毒
  • 方法一:苯基溴化镁与四氯化锡反应制得三苯基氯化锡，随之与氢氧化钠反应制得三苯基羟基锡，最后与乙酰氯反应制得薯瘟锡。
  • 外观性质:白色无气味的晶体。
  • 可燃性危险特性:受热分解有毒含锡气体
  • 用途一:用于防治水稻稻瘟病、稻曲病，甜菜的褐斑病等
  • 职业标准:TWA 0.1 毫克 (锡)/立方米; STEL 0.2 毫克 (锡)/立方米

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Pesticides - Pesticides & Metabolites
  7. Molluscicides - Pesticides

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