tert-butyl perpivalat 过氧化新戊酸叔丁酯

CAS 927-07-1 MFCD00048254

化学结构图

927-07-1
SMILES: CC(C)(C)OOC(=O)C(C)(C)C

化学属性

Mol. FormulaC9H18O3
Mol. Weight174.27
Melting Point-17 ºC
Solubility不溶
Refractive index1.410
Flash Point68~71℃
Density0.854

别名和识别编码

Chemical Nametert-butyl perpivalat
Synonym 2,2-Dimethyl-propaneperoxoic acid tert-butyl ester tert-Butyl peroxypivalate {Chemicalbook} lupersol11 InitiatingagentPV 引发剂PV Trigonox 25W33 Peroxypivalic acid, tert-butyl ester peroxypivalic acid tert-butyl ester Kayaester P tert-butyl peroxy pivalate trigonox25-c75 Trigonox 25C75 tert-Butyl tert-valeryl peroxide Trimethylperacetic acid tert-butyl Tertbutylperoxidetert-pentanoicacidester Lupersol 11 tert.-Butylperoxypivalat21 Esperox 31M 75%inmineralspirit {C Trigonox 25/75 tert-Butyl perpivalate t-butylperoxypivalate Propaneperoxoic acid, 2,2-dimethyl-, 1,1-dimethylethyl ester tert-Butyl trimethylperoxyacetate tert-Butyl trimethylperoxyacetate 2,2-Dime 过氧化叔戊酸叔丁酯 叔丁基过氧化叔戊酸酯 tert. Butylperoxypivalat tert.-Butylperoxypivalat 2,2-二甲基过氧丙酸-1,1-二甲基乙基酯 tert-Butyl perpivalate tert-butyltrimethylperoxyacetat tert-Butyl 2,2-dimethylperoxypropionate tert-butyl peroxypivalate, 68-77% tert-Butyl peroxypivalate Propaneperoxoicacid,2,2-dimethyl-,1,1-dimethylethylester Perbutyl PV 叔丁基过氧化特戊酸酯 t-butylperoxypyvalate Kayaester P 70 t-Butyl peroxypivalate peroxypivalicacid,tert-butylester tert-Butyl 2,2-dimethylpropaneperoxoate butyl peroxypivalate tert-Butylperoxipivalat 过氧化新戊酸叔丁酯
EC Number213-147-2
CAS Number927-07-1
Chemical Name Translation过氧化新戊酸叔丁酯
InChIKeyOPQYOFWUFGEMRZ-UHFFFAOYSA-N
Wiswesser Line Notation1X1&1&VOOX1&1&1
Beilstein Registry Number1704745
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分类

  • {uni_hamburg} no charge; organic peroxide; carboxylic peracid derivative; 1fragment

相关文献及参考

  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), carbon-13 (subvol. D), and oxygen-17 (subvol. E) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

UN Number 2110 UN 2110
Warnings 危化品目录(2015)
RTECSSE0950000 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BSPII* SPI Bulletin.  (Soc. of the Plastics Industry, 250 Park Ave., New
   York, NY 10017)  Volume(issue)/page/year: 1/75-19B

Restrict 危险品

其他信息

  • EPA化学物质信息:Propaneperoxoic acid, 2,2-dimethyl-, 1,1-dimethylethyl ester(927-07-1)
  • 用途:用作氯乙烯单体悬浮聚合的引发剂，也可用作其他单体游离基聚合的引发剂。
  • PackingGroup:II
  • HazardClass:5.2
  • 外观性质:无色液体。
  • MOL 文件:927-07-1.mol
  • 生产方法:甲酸与异丁醇在硫酸催化下反应生成叔戊酸，再与三氯化磷进行酰氯化反应生成叔戊酰氯。后者与叔丁基过氧化氢在20℃下反应生成过氧化叔戊酸叔丁酯。其中，叔丁基过氧化氢是由双氧水与叔丁醇反应制取的。原料消耗(kg/t)甲酸 1000异丁酸 1250叔丁醇 1400双氧水 9570三氯化磷 820

系列性分类

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