(5-acetylthiophen-2-yl)boronicacid 5-乙酰基-2-噻吩硼酸
CAS 206551-43-1 MFCD01075681
化学结构图
SMILES: CC(=O)C1=CC=C(S1)B(O)O
化学属性
| Mol. Formula | C6H7BO3S |
|---|---|
| Mol. Weight | 169.99 |
| Melting Point | 133-138 |
| TSCA | No |
别名和识别编码
| Chemical Name | (5-acetylthiophen-2-yl)boronicacid |
|---|---|
| CAS Number | 206551-43-1 |
| Alfabeta Name | ACETYLTHIOPHENEBORONICACID 52--- |
| MDL Number | MFCD01075681 |
| Synonym | 5-乙酰基噻吩-2-硼酸 2-ACETYLTHIOPHENE-5-BORONIC ACID (2-Acetylthien-5-yl)boronic acid, (5-Acetylthien-2-yl)boronic acid, 5-Acetyl-2-thiopheneboronic acid, 5-Acetylthiophen-2-ylboronic acid, 5-Acetylthiophene-2-boronic acid 5-ACETYLTHIOPHENE-2-BORONIC ACID (2-Acetylthien-5-yl)boronic acid 5-Acetylthiophen-2-ylboronic acid 5-Acetylthiophene-2-boronic acid RARECHEM AH PB 0135 2-Acetylthiphene-2-boronic acid 5-乙酰-2-噻吩硼酸 5-Acetothiophene-2-boronic acid (2-Acetylthien-5-yl)boronic acid, (5-Acetylthien-2-yl)boronic acid, 5-Acetyl-2-thiopheneboronic acid, 5-Acetylthiophen-2-ylboronic acid, 5-Acetylthiophene-2-boronic acid 5-ACETYL-2-THIOPHENEBORONIC ACID Boronic acid, (5-acetyl-2-thienyl)- (9CI) 5-乙酰基-2-噻吩硼酸 |
| PubChem Substance ID | 125307246 |
| Reaxys-RN | 8681302 |
| EC Number | 000-000-0 |
| Beilstein Registry Number | 8681302 |
| Chemical Name Translation | 5-乙酰基-2-噻吩硼酸 |
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分类
- {SNA} Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Heteroaryl Boronic Acids, Organometallic Reagents
- {SA} Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Heteroaryl Boronic Acids, Organometallic Reagents
相关文献及参考
- 1. Barcellos, T.; et al., Stereocomplementary asymmetric bioreduction of boron-containing ketones mediated by alcohol dehydrogenases Tetrahedron Asymmetry 22 , 1772-1777, (2011)
- 2. Uno, K.; et al., In Situ Preparation of Highly Fluorescent Dyes upon Photoirradiation J. Am. Chem. Soc. 133 , 13558-13564, (2011)
- 3. Mejias, N.; et al., Water-Soluble Palladium Nanoparticles: Click Synthesis and Applications as a Recyclable Catalyst in Suzuki Cross-Couplings in Aqueous Media Eur. J. Org. Chem. , 5090-5099, (2010)
- 4. Fairlamb, I. J. S.; et al., Suzuki-Miyaura cross-couplings mediated by trans-PdBr(N-Succ)(PPh3)2: a convenient synthetic method for diarylmethanes and aryl(heteroaryl)methanes Synthesis , 508-510, (2009)
安全信息
- H315 Causes skin irritation 会刺激皮肤
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P332+P313
- P501a
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P302+P352
- P305+P351+P338
- P405 Store locked up. 上锁保管。
- P305+P351+P338+P337+P313
- P302+P350
- P337+P313
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
其他信息
- Hazard Note:Corrosive/Keep Cold
- Alfa Aesar:5-乙酰基硫代苯-2-硼酸,98% 5-Acetylthiophene-2-boronic acid, 98%(206551-43-1)
- Sigma Aldrich:206551-43-1(sigmaaldrich)
- MOL 文件:206551-43-1.mol
- 5-乙酰基-2-噻吩硼酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 L15221 5-乙酰基硫代苯-2-硼酸, 98% 5-Acetylthiophene-2-boronic acid, 98% 5g 962元 2010/05/25 L15221 5-乙酰基硫代苯-2-硼酸, 98% 5-Acetylthiophene-2-boronic acid, 98% 25g 2702元 2010/05/25 L15221 5-乙酰基硫代苯-2-硼酸, 98% 5-Acetylthiophene-2-boronic acid, 98% 1g 213元
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