Mercury(II) Thiocyanate 硫氰酸汞(II)

CAS 592-85-8 MFCD00011039

化学结构图

592-85-8
SMILES: N#CS[Hg]SC#N

化学属性

Mol. FormulaC2N2S2Hg
Mol. Weight317
Density3.71
Melting Pointca 165° dec.
TSCAYes
Flash Point120 °C
Solubility微溶于水、醇、醚,溶于铵盐、氨水、氰化钾、溶液。

别名和识别编码

Chemical NameMercury(II) Thiocyanate
Synonym MERCURIC THIOCYANATE Thiocyanicacid,mercury(2+)salt mercurythiocyanate mercuricsulfocyanide 硫氮氰酸汞 Mercury, bis(thiocyanato)- 硫氰化汞 Thiocyanic acid, mercury(2+) salt Mercury(II)thiocyanate CHLORIDE COLOR REAGENT thiocyanicacid,mercury(2++)salt MERCURY RHODANIDE MERCURY SULFOCYANIDE mercury,bis(thiocyanate) MERCURY(+2)THIOCYANATE MERCURIC SULFOCYANATE MERCURIC THIOCYANATE STOCK 硫氰酸汞 mercurydithiocyanate Mercuric sulfocyanate bis(thiocyanato)-mercur thiocyanicacid,mercury(2+)salt[qr] MERCURY(II) THIOCYANATE Mercuric sulfocyanide mercurythiocyanatehg(scn)2 CHLORIDE COLOUR REAGENT Mercury dithiocyanate thiocyanicacid,mercury(ii)salt mercurydithiocyanate[qr] Mercuric thiocyanate 硫代氰酸汞 硫氰酸汞(II)
MDL NumberMFCD00011039
PubChem Substance ID24871785
Beilstein Registry Number3561344
EC Number209-773-0
CAS Number592-85-8
Merck Number14,5890
Chemical Name Translation硫氰酸汞(II)
Wiswesser Line NotationSCN 2 &-HG-
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分类

  • {SNA} Materials Science, Mercury Salts, Metal and Ceramic Science, Salts

安全信息

WGK Germany3
RTECSXL1550000
GHS Symbol
Hazard statements
  • H300+H310+H330
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Signal word Danger
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S13 Keep away from food, drink and animal foodstuffs 远离食品、饮料和动物饲料保存;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Packing GroupII
UN Number UN1646 UN 1646 6.1/PG 2
Risk Statements
  • R33 Danger of cumulative effects 有累积作用的危险
  • R32 Contact with acids liberates very toxic gas 与酸接触释放出毒性很高的气体
  • R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有剧毒
  • R50/53
Storage condition Store at RT. Hygroscopic
Hazard Codes T+,N
Hazard Class6.1
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 24500 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 25(7),27,1981

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3500 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 25(7),27,1981

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 685 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 25(7),27,1981

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 46 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Z

其他信息

  • 毒性分级:剧毒
  • 图谱信息:硫氰酸汞(II)(592-85-8)红外图谱(IR1)
  • Alfa Aesar:硫氰酸汞(II) Mercury(II) thiocyanate(592-85-8)
  • 用途一:用于照相业
  • MOL 文件:592-85-8.mol
  • F:8
  • 爆炸物危险特性:热, 光照不稳定
  • 上游原料:硫氰酸铵
  • 储运特性:库房通风低温干燥; 与酸、食品添加剂分开存放
  • MSDS 信息:硫氰化汞(592-85-8).msds
  • 外观性质:白色无臭味的粉末或针状结晶。
  • 硫氰酸汞(II)价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80079426 硫氰酸汞(剧毒) 100g 180元 2011/08/23 80079416 硫氰酸汞(剧毒) 100g 200元 2010/06/21 196892500 硫氰酸汞(II) Mercury(II) thiocyanate 99+% 250 GR 3063元
  • Sigma Aldrich:592-85-8(sigmaaldrich)
  • 灭火剂:水, 二氧化碳, 干粉, 砂土
  • 可燃性危险特性:不可燃烧; 遇酸、或遇高热分解有毒氰化物和汞蒸气气体
  • 急性毒性:口服- 大鼠 LD50: 46 毫克/ 公斤; 口服- 小鼠 LDL0: 24.5 毫克/ 公斤
  • Acros Organics:硫氰酸汞(II) Mercury(II) thiocyanate, 99+%(592-85-8)
  • 类别:有毒物品
  • 职业标准:TLV-TWA 0.1 毫克(汞)/ 立方米; STEL 0.15 毫克(汞)/ 立方米
  • 水中溶解度(g/100ml):每100毫升水中的溶解克数: 6.3×10-2/20℃
  • 敏感性:Hygroscopic

系列性分类


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