Diantimony trioxide 三氧化锑
CAS 1309-64-4 MFCD00011214
化学结构图
SMILES: O=[Sb]O[Sb]=O
化学属性
| Mol. Formula | O3Sb2 |
|---|---|
| Mol. Weight | 292 |
| Boiling Point | 1550 °C(lit.) |
| Melting Point | 655 °C(lit.) |
| Density | 5.67 |
| TSCA | Yes |
| Solubility | Slightly soluble in water, Slowly dissolves in warm HCl or warm KOH solutions |
| Flash Point | 1550°C subl. |
| Stability | 对湿度敏感 |
| Appearance | powder |
别名和识别编码
| Chemical Name | Diantimony trioxide |
|---|---|
| CAS Number | 1309-64-4 |
| PubChem Substance ID | 24863233 |
| EC Number | 215-175-0 |
| MDL Number | MFCD00011214 |
| Merck Number | 14,711 |
| Synonym | Dechlorane A-O Antimony sesquioxide Exitelite a1530 antox A 1588LP 三氧化二锑,锑白 Antimony trioxide production {Chemicalbook} antimonyperoxide Nyacol A 1530 Weisspiessglanz Fireshield FSPO 405 Chemetron fire shield Amspec-KR 氧化锑, 99.9% (METALS BASIS) DI-ANTIMONY TRIOXIDE ANTIMONY OXIDE antimonyoxide(o3sb2) ANTIMONY(+3)OXIDE {hazard_c AP 50 Stibiox MS a1582 氧化锑, 99.6% MIN Thermoguard L antimonywhite Patox S 锑氧 Antimony(III) oxide; Antimony trioxid {C Antimonious oxide Timonox antimonysesquioxide 无水亚锑酸 Atox F 锑白 ANTIMONOUS OXIDE 氧化锑, PURATRONIC|R, 99.999% (METALS BASIS) Patox H Thermoguard B Twinkling star Antimony(3+) oxide antimonyoxideo3sb2 三氧化二锑 Timonox White Star Patox L Antimony trioxide Antimony Whi AT 3 (fireproofing agent) 亚锑酸酐 氧化亚锑,锑华,锑白,亚锑酸酐 C.I. Pigment White 11 antimonytrioxideproduction {ha 亚锑酐 锑华 C.I.颜料白 11 ANTIMONY TRIOXIDE 氧化亚锑 氧化銻 White star a1588lp antimoniousoxide amspec-kr Flowers of antimony SB OXIDE |
| Chemical Name Translation | 三氧化锑 |
| Wiswesser Line Notation | .SB2.O3 |
| LabNetwork Molecule ID | LN04603632 |
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分类
- {SNA} Alternative Energy, Antimony, Catalysis and Inorganic Chemistry, Chemical Synthesis, Dopants, Materials Science
- {SNA} 51: Sb,
- {SNA} Alternative Energy, Antimony, Dopants, Metal and Ceramic Science, Oxides, Phosphors - Phosphor Materials, 材料科学
- {SNA} Alternative Energy, Antimony,
- {SNA} 51: Sb, Antimony, Catalysis and Inorganic Chemistry, Chemical Synthesis, Metal and Ceramic Science, Nanomaterials, Nanoparticles: Materials by Application, Nanoparticles: Oxides, Nitrides, and Other Cera
- {SNA} 3D Printing Materials for Research and Development, Alternative Energy, Antimony,
相关文献及参考
- Merck: 14,711
安全信息
GHS Symbol
- H351 Suspected of causing cancer 怀疑致癌
- P281 Use personal protective equipment as required. 使用所需的个人防护装备。
- S22 Do not breathe dust 不要吸入粉尘；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
TYPE OF TEST : TC - Toxic concentration (other than lowest) ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 4 mg/m3/1Y-I TOXIC EFFECTS : Tumorigenic - equivocal tumorigenic agent by RTECS criteria Lungs, Thorax, or Respiration - tumors Liver - tumors REFERENCE : PESTC* Pesticide & Toxic Chemical News. (Food Chemical News, Inc., 400 Wyatt Bldg., 777 14th St., NW, Washington, DC 20005) V.1- 1972- Volume(issue)/page/year
TYPE OF TEST : TCLo - Lowest published toxic concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 4200 ug/m3/52W-I TOXIC EFFECTS : Tumorigenic - Carcinogenic by RTECS criteria Lungs, Thorax, or Respiration - tumors Liver - tumors REFERENCE : AIHAM* Annual Meeting of American Industrial Hygiene Association. (Akron, OH) F
TYPE OF TEST : TC - Toxic concentration (other than lowest) ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 50 mg/m3/7H/52W-I TOXIC EFFECTS : Tumorigenic - Carcinogenic by RTECS criteria Lungs, Thorax, or Respiration - tumors REFERENCE : JTEHD6 Journal of Toxicology and Environmental Health. (Hemisphere Pub., 1025 Vermont Ave., NW, Washington, DC 20005) V.1- 1975/76- Volume(issue)/page/year: 18,607,1986
TYPE OF TEST : TC - Toxic concentration (other than lowest) ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 4 mg/m3/1Y-I TOXIC EFFECTS : Tumorigenic - equivocal tumorigenic agent by RTECS criteria Lungs, Thorax, or Respiration - tumors Liver - tumors REFERENCE : PESTC* Pesticide & Toxic Chemical News. (Food Chemical News, Inc., 400 Wyatt Bldg., 777 14th St., NW, Washington, DC 20005) V.1- 1972- Vo
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : >34600 mg/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) Skin and Appendages - hair REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555447
TYPE OF TEST : LD - Lethal dose ROUTE OF EXPOSURE : Subcutaneous SPECIES OBSERVED : Mammal - species unspecified DOSE/DURATION : >120 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 8(7),25,1964
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 2 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555447
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Subcutaneous SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 2500 ug/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden
TYPE OF TEST : DNA repair TEST SYSTEM : Bacteria - Bacillus subtilis DOSE/DURATION : 50 mmol/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 77,109,1980
TYPE OF TEST : Sister chromatid exchange TEST SYSTEM : Rodent - hamster Lung DOSE/DURATION : 90 ug/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 264,163,1991
TYPE OF TEST : TCLo - Lowest published toxic concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE : 270 ug/m3/24H SEX/DURATION : female 1-21 day(s) after conception TOXIC EFFECTS : Reproductive - Fertility - pre-implantation mortality (e.g. reduction in number of implants per female; total number of implants per corpora lutea) Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants) Reproductive - Effects on Embryo or Fetus - fetal death REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 54(4),68,1989
TYPE OF TEST : TCLo - Lowest published toxic concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE : 82 ug/m3 SEX/DURATION : female 1-21 day(s) after conception TOXIC EFFECTS : Reproductive - Fertility - pre-implantation mortality (e.g. reduction in number of implants per female; total number of implants per corpora lutea) Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 52(10),85,1987
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Intratesticular SPECIES OBSERVED : Rodent - rat DOSE : 23320 ug/kg SEX/DURATION : male 1 day(s) pre-mating TOXIC EFFECTS : Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count) Reproductive - Paternal Effects - testes, epididymis,
其他信息
- 用途四:用作各种树脂、合成橡胶、帆布、纸张、涂料等的阻燃剂，石油化工、合成纤维的催化剂。用于制造媒染剂、乳白剂，是合成锑盐的原料。搪瓷工业用作添加剂，以增加珐琅的不透明性和表面光泽。玻璃工业用作代替亚砷酸的脱色剂。医药、冶金、军工等。
- 锑氧化合物:三氧化二锑与四氧化锑、五氧化锑是目前具有工业用途的三种锑与氧形成的化合物，锑与氧可形成一系列氧化物，其中有Sb2O3、Sb2O4、Sb2O5、Sb6O13、Sb2O及气态的SbO，但只有前三种在工业生产上具有意义，其他氧化物多为锑的不同生产过程中的过渡产物。 三氧化二锑(Sb2O3，Mr291.50)是双型的物质，有立方晶型和单斜晶型两种。晶型不同，密度和折射率略有差异。立方晶型的密度和折射率分别为5.2和2.087，而单斜晶型则分别为5.67和2.180。平常由SbCl3水解生成的Sb2O3是斜方结晶体，在惰性气体或真空中灼烧至红热，升华而得到正方形结晶。三氧化二锑是白色粉末，密度为5.67g/cm3，加热时变黄色，冷却后又变为白色。在656℃时熔成淡黄色或灰色液体，冷却后又变成白色石棉状带丝光的物质。三氧化二锑微溶于水、乙醇和稀酸，易溶于浓盐酸、草酸和酒石酸溶液，也溶于发烟硝酸和发烟硫酸; 溶于碱中形成锑酸盐。三氧化二锑的毒性不大，但对鼻、眼、喉及呼吸道等器官有刺激性作用，接触皮肤可诱发皮炎。三氧化二锑主要有干法和湿法两种制备方法。干法是将硫锑矿锻烧生成的粗三氧化二锑在焦炭存在下，用纯碱作助熔剂还原为金属锑，再经空气氧化制得纯三氧化二锑。湿法是将硫锑矿用盐酸浸出生成三氯化锑，再用苛性钠水解而得。 三氧化二锑的两种晶型 以上信息由Chemicalbook的晓楠编辑整理。
- 用酒石酸锑钾制取三氧化二锑:把氨水加入酒石酸锑钾的沸液中 (一份酒石酸锑钾K(SbO) C4H4O6溶于10份水中)，煮沸一段时间，过滤、洗涤后即得到三氧化二锑。 其中水解法所制备的三氧化二锑经光谱定性分析仅检出了痕量的硅、镁。适于作光谱分析标准。 在500ml烧杯中加入15g分析纯三氧化锑，再加入30ml高纯盐酸 (1+1)，在搅拌下使之溶解。用洗净的玻璃砂漏斗抽滤溶液，除去不溶性杂质，然后用高纯水将滤液稀释至400ml，此时析出白色氯氧化锑的沉淀。等溶液澄清后，将清液倾出，用倾泻法洗涤沉淀数次。在洗好的沉淀中，加入高纯氨水 (1+25
- 用途三:用作高纯试剂、媒染剂及防光剂，也用于颜料及酒石酸锑钾的制备
- 方法一:锑白的制备方法分为干法和湿法两种。干法包括金属锑法和辉锑矿法；湿法包括酸浸法和锑盐分解法。 干法 金属锑法（干法）。反应方程式： Sb+O2→Sb2O3 操作方法： 700 kg 99.8%金属锑（含29×10 -6 的硫）在石墨炉中加热至1200℃,以0.3m 3 /min通空气5min，直至排气中二氧化硫含量≤5×10 -6 ，冷却至786℃,以2m 3 /min速度鼓空气12h，得锑白收率为92.1%。 辉锑矿法（干法）。反应方程式： 2Sb2S3+9O2→2Sb2O3+6SO2↑ Sb2O3+3C→2Sb+3CO↑ 4Sb+O2→2Sb2O3 操作方法： 选择高品位辉锑矿含Sb 50%～60%,As 0.1%,Pb 0.007%，Fe 0.16%， S 11.42%, Al2O3 0.66%，CaO 4.75%，MgO<;0.5%, SiO2 8.65%， HgO 0.0026%。将此精矿与占锑精矿量10%的铁矿（Fe 50.17%)和2%石灰石 （CaO>;50%）混合，按一定速度加入烟化炉液渣熔池，鼓入空气、煤粉混合物以调节液渣的温度和炉内气氛，使温度保持在1250℃左右，炉内气相中CO2/CO为4.78, 1 g PO2=-8.33，加入炉料不断熔化，锑主要以Sb2O3、少量以硫化物形态不断烟化进入气相，在净化烟气时，经烟道及燃烧室吸风燃烧，把硫化物转化为Sb2O3，烟气中的氧化物随后在各段收尘设备中分别收集之。其中烟道旋涡收集的为锑氧，电收尘器收集的烟尘纯度较高，可作为锑白使用，收
- 毒性分级:中毒
- 急性毒性:腹腔-大鼠 LD50: 3250 毫克/公斤; 腹腔-小鼠 LD50: 172 毫克/公斤
- 常规方法:试剂用玻璃瓶装，每瓶净重500g。其他用内衬聚乙烯塑料袋的塑料编织袋或铁桶包装，每袋或桶净重50kg。 贮存于阴凉干燥的库房中。勿与无机浓酸、烧碱共贮混运。运输过程中要防雨淋、防日晒、避光，密封保存。
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