Thallium(I) Chloride 氯化铊

CAS 7791-12-0 MFCD00011274

化学结构图

7791-12-0
SMILES: Cl[Tl]

化学属性

Mol. FormulaTlCl
Mol. Weight239.84
Density7 g/mL at 25 °C(lit.)
Melting Point430 °C(lit.)
Refractive index2.247
TSCAYes
SolubilitySlightly soluble in cold water, more soluble in boiling water
Vapor Pressure10 mmHg ( 517 °C)
Boiling Point720 °C/1 atm(lit.)
Appearance beads

别名和识别编码

Chemical NameThallium(I) Chloride
Synonym THALLOUS CHLORIDE 氯化铊(I) 氯化亚铊 thallouschloride0 Thallous chloride TI 201 TlCl Thallium monochloride 氯化鉈 Rcra waste number U216 Thalliumchlorid Thallium(I) chloride, 99.995% Thallous chloride THALLIUM(I) CHLORIDE, 99.999% 一氯化铊 RCRA waste number U216 Thallium(I)-chlorid Thallium(I) chloride Thalium(I) chloride thallium (I) chloride THALLIUM CHLORIDE Thallium(1+) chloride THALLIUM (OUS) CHLORIDE Thallium chloride Thallium(Ⅰ)chloride Thallium chloride (TlCl) Thallium chloride, (TlCl) THALLIUM(I) CHLORIDE ANHYDROUS BEADS & 氯化铊(I), 99.999% (METALS BASIS) 氯化铊 thalliumchloride(tlcl) 氯化铊(I), ULTRA DRY, 99.999% (METALS BASIS) THALLIUM(I) CHLORIDE Thallium chloride (thallous) THALLIUM(+1)CHLORIDE Thallium(I)chlorid rcrawastenumberu216 Thallium(I)chloride,99.999%(metalsbasis) 氯化铊(I), 99.9% (METALS BASIS)
CAS Number7791-12-0
EC Number232-241-4
MDL NumberMFCD00011274
Merck Number14,9260
PubChem Substance ID24642
Chemical Name Translation氯化铊
Wiswesser Line NotationTL G
LabNetwork Molecule IDLN02144344
InChIInChI=1S/ClH.Tl/h1H;/q;+1/p-1
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Materials Science, Metal and Ceramic Science, Research Essentials, Salts,
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts, Thallium, Thallium Salts, 材料科学
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Salts, Thallium, Thallium Salts, Tl, Ultra-High Purity Materials
  • {SNA} Catalysis and Inorganic Chemistry,
  • {SNA} Catalysis and

相关文献及参考

  • Grocholl, L. et al. Inorg. Chem. 37 , 2496, (1998)
  • Merck 14 ,9260
  • Corp MSDS 1 (2), 3316:B / RegBook 1 (3), 3323:F / Sax 6 , 2556
  • Short: III/29a Title: Low Frequency Properties of Dielectric Crystals: Second and Higher Order Elastic Constants Author: Every, A.G.; McCurdy, A.K. Editor: Nelson, D.F. Source: Landolt-Börnstein, New Series Volume: III/29a Year: 1992 ISBN: 3-540-54410-0 ISBN: 978-3-540-54410-4 Internet Resource: DOI:10.1007/b44185 RefComment: 890 figs., XIV, 743 pages. Hardcover Abstract: Some years after the publication of Vol. III/11 and its supplement III/18 dealing with elastic, piezoelectric, pyroelectric and optical properties of crystals, a complete recompilation of the data of these volumes and of new data was performed. Because of the growth of this subject matter it was found convenient to divide the material into four volumes, III/29a and b for the low frequency properties and III/30a and b for high frequency propertiesof dielectric crystals. The first subvolume III/29a contains exclusively second and higher order elastic constants including temperature and pressure coefficients.
  • Short: III/30A Title: High Frequency Properties of Dielectric Crystals: Piezooptic and Electrooptic Constants Author: Cook, W.R.; Nelson, D.F.; Vedam, K. Editor: Nelson, D.F. Source: Landolt-Börnstein, New Series Volume: III/30A Year: 1996 Keyword: Dielectric Crystals; High Frequency Properties; Piezooptic and Electrooptic ISBN: 3-540-54412-7 ISBN: 978-3-540-54412-8 Internet Resource: DOI:10.1007/b44186 RefComment: 411 figs., XII, 497 pages, Hardcover Abstract: While vols. III/29 A, B (published in 1992 and 1993, respectively) contain the low frequency properties of dielectric crystals, in vol. III/30 the high frequency or optical properties are compiled. The present and first subvolume 30 A contains piezooptic and elastooptic constants, linear and quadratic electroop

安全信息

GHS Symbol
WGK Germany3
Hazard Codes T+,N
Hazard statements
  • H330 Fatal if inhaled 吸入致命
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H300 Fatal if swallowed 吞食致命
  • H300+H330
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSXG4200000
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Signal word Danger
UN Number UN 1707 6.1/PG 2 UN1707
Risk Statements
  • R51/53
  • R26/28 Very toxic by inhalation and if swallowed 吸入及吞食都有剧毒
  • R33 Danger of cumulative effects 有累积作用的危险
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S13 Keep away from food, drink and animal foodstuffs 远离食品、饮料和动物饲料保存;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
Storage condition Air Sensitive Poison room
Packing GroupII
Hazard Class6.1
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 150 mg/kg
TOXIC EFFECTS :
   Gastrointestinal - hypermotility, diarrhea
   Kidney, Ureter, Bladder - other changes
REFERENCE :
   TRENAF Kenkyu Nenpo--Tokyo-toritsu Eisei Kenkyusho.  Annual Report of Tokyo
   Metropolitan Research Laboratory of Public Health.  (Tokyo-toritsu Eisei
   Kenkyusho, 24-1, 3-chome, Hyakunin-cho, Shin-juku-ku, Tokyo 160, Japan) V.1-
      1949/50-  Volume(issue)/page/year: 11,167,1959

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 6900 ug/kg
TOXIC EFFECTS :
   Brain and Coverings - encephalitis
   Gastrointestinal - other changes
   Skin and Appendages - hair
REFERENCE :
   85ECAN "Metal Toxicity in Mammals, Vol. 2: Chemical Toxicity of Metals and
   Metalloids," Venugopal, B., and T.D. Luckey, New York, Plenum Press, 1978
   Volume(issue)/page/year: 2,101,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 24 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HYSAAV Hygiene and Sanitation (USSR).  English translation of GISAAA.
   (Springfield, VA)  1964-71. Discontinued.  Volume(issue)/page/year:
   29(2),26,1964

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 23982 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   COREAF Comptes Rendus Hebdomadaires des Seances, Academie des Sciences.
   (Paris, France)  V.1-261,

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - hamster Embryo
DOSE/DURATION           : 100 umol/L
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   39,193,1979

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 30 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 24(2),46A,1981

其他信息

  • 外观性质:无色或白色粉末或结晶,在空气及光线中变成紫色。
  • 毒性分级:剧毒
  • 可燃性危险特性:不可燃物质; 受热产生有毒氯化物和含铊化物烟雾
  • MOL 文件:7791-12-0.mol
  • Sigma Aldrich:7791-12-0(sigmaaldrich)
  • 急性毒性:腹腔- 大鼠 LDL0: 6.9 毫克/ 公斤; 口服- 小鼠 LD50: 24 毫克/ 公斤
  • 敏感性:Air Sensitive
  • 图谱信息:氯化铊(7791-12-0)红外图谱(IR1)
  • 蒸气压:10 mm Hg ( 517 °C)
  • 氯化铊价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 208880250 氯化铊 Thallium(I) chloride 99% 25 GR 779元 2010/06/21 208881000 氯化铊 Thallium(I) chloride 99% 100 GR 2464元 2010/05/25 36344 氯化铊(I), 99.9% (metals basis) Thallium(I) chloride, 99.9% (metals basis) 25g 1442元
  • 储运特性:库房通风低温干燥; 与碱、酸类、食品添加剂分开存放
  • Alfa Aesar:氯化铊(I),ultradry,99.999%(metalsbasis) Thallium(I) chloride, ultra dry, 99.999% (metals basis)(7791-12-0)
  • MSDS 信息:氯化铊(7791-12-0).msds
  • Acros Organics:氯化铊 Thallium(I) chloride, 99%(7791-12-0)
  • 职业标准:TLA-TWA 0.1 毫克(铊)/ 立方米
  • 类别:有毒物品

系列性分类


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