Gold(I) Potassium Cyanide 氰金酸(I)钾

CAS 13967-50-5 MFCD00011414

化学结构图

13967-50-5
SMILES:

化学属性

Mol. FormulaC2AuKN2
Mol. Weight288.33
Density3.45
Melting Pointdec.
TSCAYes
Appearance 氰化亚金钾(13967-50-5)为白色晶体粉末；热至200℃时失去结晶水，更高温度分解。溶解性:溶于水，微溶于醇，不溶于醚。易受潮。

别名和识别编码

Chemical NameGold(I) Potassium Cyanide
Synonym Gold potassium cyanide Potassium cyanoaurate(I) Aurate(1-), bis(cyano-kappaC)-, potassium gold(i) potassium cyanide, premion POTASSIUM GOLD CYANIDE Monopotassium dicyanoaurate Gold potassium cyanide (KAu(CN)2) Gold(I)potassiumcyanide,Premion,99.99%(metalsbasis),Au67.8%min Aurate(1-), dicyano-, potassium Kaliumgoldcyanid Aurate(1-), bis(cyano-C)-, potassium Gold potassium cyanide, kau(cn)2 Potassium dicyanoaurate(1-) Potassium dicyanoaurate(I), 99+% 氰金(I)酸钾 Gold (I) potassium cyanide POTASSIUM AUROCYANIDE 金氰化钾; 二氰合金酸钾; 氰亚金酸钾; 氰化亚金钾 Aurate(1-), bis(cyano-κC)-, potassium Potassium aurocyanide (KAu(CN)2) Gold(I) potassium cyanide GOLD(I) POTASSIUM CYANIDE Kaliumdicyanoaurat-(I) GOLD POTASSIUM CYANIDE Potassium dicyanoaurate (KAu(CN)2) Potassium dicyanaurate POTASSIUM DICYANOAURATE(I) Gold potassium cyanide (AuK(CN)2) Kaliumdicyanoaurat(I) Potassium dicyanoaurate(I) POTASSIUM DICYANOAURATE(+1) POTASSIUM GOLD(I) CYANIDE POTASSIUM CYANOAURATE Potassium aurocyanide POTASSIUM GOLD(+1)CYANIDE
PubChem Substance ID24857959
EC Number237-748-4
Beilstein Registry Number6235525
MDL NumberMFCD00011414
CAS Number13967-50-5
Merck Number14,7628
Chemical Name Translation氰金酸(I)钾
InChIKeyXTFKWYDMKGAZKK-UHFFFAOYSA-N
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分类

  • {Chemicalbook} 无机化工产品: 无机盐: Cg氰化物
  • {SNA} Materials Science, Metal and Ceramic Science, Potassium Salts, Salts
  • {uni_hamburg} no charge; metal-organic; cyanide; 2fragments; ionic

相关文献及参考

  • Short: III/31a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cu Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/31a Year: 1993 Keyword: NQR ISBN: 3-540-55146-8 ISBN: 978-3-540-55146-1 Internet Resource: DOI:10.1007/b43999 RefComment: VIII, 437 pages. Hardcover Abstract: Volume III/31 continues the compilation of nuclear quadrupole resonance spectroscopy data of solid substances which started in with volume III/20 in 1987 covering the literature from the beginning of nuclear quadrupole resonance spectroscopy in 1951 to 1982 and containing the data for 8000 substances in the solid state, distributed among three subvolumes III/20 a, b, and c. Volume III/31 covers the literature published in the period from the end of 1982 through the end of 1989. Included are the data for substances studied for the first time, as well as data for substances already present in the previous volume III/20 if the data published there could be completed or improved by new studies. In total there are 2500 substances in volume III/31, showing the scope and significance of nuclear quadrupole resonance spectroscopy up to recent times.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H330 Fatal if inhaled 吸入致命
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H310 Fatal in contact with skin 皮肤接触致命
  • H300 Fatal if swallowed 吞食致命
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Signal word Danger
RTECSCK6270000
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S29 Do not empty into drains 不要排入下水道；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S7 Keep container tightly closed 保存在严格密闭容器中；
  • S22 Do not breathe dust 不要吸入粉尘；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Packing GroupII
UN Number UN1588 UN 1588 6.1/PG 1
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R32 Contact with acids liberates very toxic gas 与酸接触释放出毒性很高的气体
  • R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有剧毒
  • R50/53
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R38 Irritating to skin 刺激皮肤
Hazard Codes T T+,N
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品

其他信息

  • MOL 文件:554-07-4.mol
  • 可燃性危险特性:不燃; 遇水, 潮气和酸分解有毒氰化氢气体
  • 上游原料:盐酸 --> 硝酸 --> 氢氧化铵 --> 氰化钾 --> 金
  • 储运特性:库房通风低温干燥; 与氯酸盐, 亚硝酸钠 (钾) 分开储运
  • 灭火剂:雾状水
  • 毒性分级:剧毒
  • 爆炸物危险特性:与氯酸盐, 亚硝酸钠 (钾) 混合可爆
  • 用途一:广泛用于电子、信息、航天、航空等高科技领域
  • 类别:有毒物品

系列性分类

  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Salts 金属盐
  4. Potassium Salts - Salts

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