(2-Ethoxy-2-Oxoethyl)Triphenylphosphonium Chloride (2-乙氧基-2-氧乙基)三苯基氯化膦

CAS 17577-28-5 MFCD00011746

化学结构图

17577-28-5
SMILES: [Cl-].CCOC(=O)C[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaC22H22ClO2P
Mol. Weight385
Melting Point120-123
TSCAYes

别名和识别编码

Chemical Name(2-Ethoxy-2-Oxoethyl)Triphenylphosphonium Chloride
Synonym (2-Ethoxy-2-oxoethyl)triphenylphosphonium chloride (Carboethoxymethyl)triphenylphosphonium chloride (Carboethoxymethyl)triphenylphosphonium chlorideEthyl (triphenylphosphonio)acetate chloride Ethyl (triphenylphosphonio)acetate chloride
CAS Number17577-28-5
PubChem Substance ID24845340
EC Number241-548-2
Beilstein Registry Number3924139
MDL NumberMFCD00011746
Chemical Name Translation(2-乙氧基-2-氧乙基)三苯基氯化膦
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分类

  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

相关文献及参考

  • 1. Voelker, T.; et al. Bioorg. Med. Chem. 17 , 2047, (2009)
  • 2. Mico, X. A.; et al. Tetrahedron Lett. 47 , 7845, (2006)
  • 3. Boruwa, J.; et al. Org. Biomolecular Chem. 4 , 3521, (2006)
  • 4. Rao, V. V. V. N. S. R.; et al. ARKIVOC , 211, (2005)
  • 5. Brovarets, V. S.; et al. Russ. J. Gen. Chem. 72 , 1828, (2002)
  • 6. O. Sieber et al. Helv. Chim. Acta 40 , 1242, (1957)
  • 7. H.J. Bestmann et al. Chem. Ber. 96 , 465, (1963)
  • 8. H. Moison et al. Tetrahedron 43 , 537, (1987)
  • Beil. 16 ,IV,988
  • Corp MSDS 1 (1), 1555:C / FT-IR 2 (2), 3338:B / RegBook 1 (2), 2279:C / Structure Index 1 , 356:D:8

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Hygroscopic

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination

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