Tetraphenylphosphonium iodide 四苯基鏻碘

CAS 2065-67-0 MFCD00011917

化学结构图

2065-67-0
SMILES: [I-].c1ccc([P+](c2ccccc2)(c2ccccc2)c2ccccc2)cc1

化学属性

Mol. FormulaC24H20IP
Mol. Weight466.29
Melting Point343-348 °C
TSCANo
Flash Point280 °C

别名和识别编码

Chemical NameTetraphenylphosphonium iodide
Synonym Tetraphenylphosphonium iodide {LY} Tetraphenylphosphonium iodide {} {LY} Tetraphenylphosphonium iodide {} {} {LY} Tetraphenylphosphonium iodide {} {} {} {LY} Tetraphenylphosphonium iodide {} {} {} {} {LY} Tetraphenylphosphonium iodide {} {} {} {} {} {LY} Tetraphenylphosphonium iodide {} {} {} {} {} {} {LY} Tetraphenylphosphonium iodide {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium iodide {} {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium iodide {} {} {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium iodide {} {} {} {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium iodide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium iodide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium iodide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium iodide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraphenylphosphoniu
MDL NumberMFCD00011917
CAS Number2065-67-0
PubChem Substance ID2724164
Beilstein Registry Number3922216
EC Number218-179-0
Reaxys-RN3922216
Chemical Name Translation四苯基鏻碘
LabNetwork Molecule IDLN01746620
InChIKeyAEFPPQGZJFTXDR-UHFFFAOYSA-M
InChIInChI=1S/C24H20P.HI/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;/h1-20H;1H/q+1;/p-1
Canonical SMILESC1=CC=C(C=C1)[P+](C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.[I-]
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 2fragments; ionic

相关文献及参考

  • Applications of the Pd-catalyzed cleavage of the P-C bond to organic synthesis have been reported: Chem. Lett., 1101 (1995).
  • Short: III/5b
  • Has found use as a phase-transfer catalyst (see Appendix 2), more thermally stable than the corresponding bromide or chloride in the presence of base: Tetrahedron Lett., 349 (1979).
  • Short: EINECS

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture Light Sensitive {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, aw
Hazard Codes Xn

其他信息

  • Acros Organics:四苯基碘化膦 Tetraphenylphosphonium iodide, 99%(2065-67-0)
  • F:8
  • Alfa Aesar:四苯基碘化膦,98+% Tetraphenylphosphonium iodide, 98+%(2065-67-0)
  • TCI Shanghai:四苯基膦碘 Tetraphenylphosphonium Iodide,>;97.0%(T)(2065-67-0)
  • Sigma Aldrich:2065-67-0(sigmaaldrich)
  • 四苯基碘化膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1450 四苯基碘化膦 Tetraphenylphosphonium Iodide 25G 1040元 2014/06/02 T1450 四苯基碘化膦 Tetraphenylphosphonium Iodide 10G 588元 2010/06/21 204040100 四苯基碘化膦 Tetraphenylphosphonium iodide 99% 10 GR 797元
  • MOL 文件:2065-67-0.mol
  • 敏感性:Light Sensitive

系列性分类


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